Heat-Insulating Cement Slurry for Hydrate Layer Stability

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Solution Overview

Problem

Deep-water oil and gas production is hindered by the thermal decomposition of gas hydrates in penetrated hydrate layers, leading to cement seal integrity failure and potential blowouts, as existing low-temperature, early-strength, and low-hydration cement slurry systems do not adequately address the heat insulation needs near hydrate layers.

Innovation Solution

A performance evaluation device and design method for a low-hydration, early-strength, and heat-insulating cement slurry system, which includes a thermal insulation layer and a simulation setup to evaluate the cement's thermal insulation performance, using materials like hollow glass microspheres, perlite, or vitrified micro bubbles to maintain hydrate stability during production.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If low-temperature, early-strength, and low-hydration cement slurry systems are used, then hydrate decomposition during wait-on-cement is reduced, but thermal insulation capacity of the cement sheath is insufficient to prevent heat transfer from wellbore to formation during production

Engineering Contradiction:
Improvecement seal integrityVSAvoidthermal insulation capacity
Core Design Contradiction:
ReliabilityVSTemperature

Solution Approach 1:

The patent develops a composite cement slurry system incorporating heat-insulating materials (such as perlite, vermiculite, or foam glass beads) suspended in the cement matrix. This composite structure combines the sealing and structural properties of cement with the thermal insulation properties of the embedded materials, achieving both reliable cement seal integrity and sufficient thermal insulation capacity to prevent hydrate decomposition during production

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent modifies the thermal parameters of the cement slurry by controlling the type, quantity, and distribution of heat-insulating additives. By adjusting the volume fraction of insulation materials and their particle size distribution, the cement sheath's thermal conductivity is reduced to maintain hydrate stability while preserving early strength development and seal integrity

Inventive Principle:
Principle #35Parameter changes

2Temperature

If heat insulation capacity of cement sheath is improved to prevent hydrate decomposition, then thermal insulation performance increases, but device complexity and material selection complexity increase

Engineering Contradiction:
Improvethermal insulation capacityVSAvoidmaterial selection complexity
Core Design Contradiction:
TemperatureVSDevice complexity

Solution Approach 1:

The patent utilizes porous heat-insulating materials (perlite, vermiculite, foam glass beads) that can be easily incorporated into cement slurry. These materials provide high insulation performance with simple processing requirements and well-established handling procedures, avoiding the need for complex device modifications or sophisticated material application techniques

Inventive Principle:
Principle #31Porous materials

Solution Approach 2:

The patent provides specific guidance on the volume fraction ranges of heat-insulating additives (typically 10-50% by volume) and their optimal particle size distributions to achieve desired thermal insulation performance. This parameter-based approach simplifies material selection and formulation by providing clear design criteria rather than requiring extensive experimental optimization

Inventive Principle:
Principle #35Parameter changes

3Strength

If conventional cement slurry is used, then early strength is achieved, but hydration heat causes hydrate layer decomposition and cementing quality decline

Engineering Contradiction:
Improveearly strengthVSAvoidhydration heat
Core Design Contradiction:
StrengthVSObject-generated harmful factors

Solution Approach 1:

The patent selects low-hydration-heat cement types (such as sulfate-resistant Portland cement or blended cements with pozzolanic materials) and adjusts the water-cement ratio and admixture composition to reduce the peak hydration temperature. This allows the cement to develop sufficient early strength while generating less heat that would otherwise decompose the hydrate layer

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent incorporates heat-insulating materials into the cement slurry matrix, creating a composite system where the insulation materials act as thermal barriers within the cement structure. This reduces the temperature rise during hydration and maintains a more stable thermal environment for hydrate stability, while the cement matrix continues to provide early strength development

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The low-hydration, early-strength, and heat-insulating cement slurry system effectively isolates penetrated hydrate layers, ensuring stability and preventing accidents by reducing heat conductivity and maintaining hydrate integrity during well cementing and production processes.

Implementation Method 1

a thermal insulation layer arranged on an outer wall of the outer cavity body

Methodology Applied
Scientific EffectThermal insulation: Thermal Insulation

Implementation Method 2

improve the thermal insulation capacity of a cement sheath near the hydrate layer

Methodology Applied
Scientific EffectThermal insulation: Thermal Insulation

Data Source

PatentUS11719658B2Method of cement for well cementing in penetrated hydrate layer
Publication Date: 2023.08.08 CHINA UNIV OF PETROLEUM (EAST CHINA)
  • US11719658B2 patent drawing
  • US11719658B2 patent drawing
  • US11719658B2 patent drawing

AI summary

A performance evaluation device and a design method of a cement for well cementing in a penetrated hydrate layer are provided. The performance evaluation device includes an equivalent wellbore, an inner circulation system, an outer circulation system, a thermal insulation cover, a bracket, a temperature sensing system, and a cement mold. The device can simulate a true downhole situation, conduct an evaluation experiment on the heat insulation performance of a cementing cement, and conduct experiments at different temperatures with automatic temperature control. The design method is to use a low-hydration, early-strength, and heat-insulating cement slurry system during the well cementing in a penetrated hydrate layer, where the low-hydration and early-strength characteristics ensure the effective sealing of a hydrate layer during a cementing process, and the heat insulation characteristic results in low heat conductivity and thus can ensure the stability of a hydrate layer during a production operation.