Heat Integration in Gas Processing Shift Reactors

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

Integrated gasification combined cycle (IGCC) and substitute natural gas (SNG) plants face significant energy inefficiencies due to waste energy generation and high energy demands in gas treatment processes, particularly in converting carbonaceous feedstocks into syngas, where substantial steam is required and often wasted.

Innovation Solution

The implementation of heat integration within gas processing units, utilizing exothermic shift reactions to produce steam, which is then used as a heat transfer medium and power source, reducing the overall steam requirement by up to two-fold and minimizing irreversible heat losses through efficient heat recovery and utilization.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Use of energy by moving object

If heat integration is implemented using exothermic shift reactions to produce steam, then energy efficiency is improved and steam consumption is reduced, but system complexity increases due to additional heat exchange equipment

Engineering Contradiction:
Improveenergy efficiencyVSAvoidsystem complexity
Core Design Contradiction:
Use of energy by moving objectVSDevice complexity

Solution Approach 1:

The patent combines the steam generation function with the gas cooling function by integrating heat exchangers within the gas processing section. The exothermic heat from shift reactions is merged with the cooling requirement of the gas stream, allowing simultaneous steam production and gas temperature control through a unified heat integration system.

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The heat exchangers serve multiple functions: they cool the hot gas stream from shift reactions, generate steam for process use, and preheat feed water. This multi-functionality reduces the need for separate equipment and improves overall energy utilization efficiency.

Inventive Principle:
Principle #6Universality (Multi-functionality)

2Quantity of substance

If steam is generated from exothermic shift reactions, then steam requirement is reduced, but irreversible heat losses increase without proper heat recovery

Engineering Contradiction:
Improvesteam requirementVSAvoidirreversible heat losses
Core Design Contradiction:
Quantity of substanceVSLoss of energy

Solution Approach 1:

The patent implements preliminary heat recovery by using heat exchangers to capture heat from the hot gas stream before it exits the system. This pre-recovery action prevents irreversible heat losses by utilizing the thermal energy while the gas is still at high temperature, generating steam that can be used elsewhere in the process.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The heat integration system maintains continuous useful action by constantly recovering heat from the gas stream and converting it to steam. This continuous process ensures that thermal energy is utilized throughout operation rather than being lost, maintaining energy efficiency consistently.

Inventive Principle:
Principle #20Continuity of useful action

3Loss of energy

If multiple steam generators are installed between shift reactors, then heat recovery efficiency is improved, but device complexity and capital cost increase

Engineering Contradiction:
Improveheat recovery efficiencyVSAvoiddevice complexity
Core Design Contradiction:
Loss of energyVSDevice complexity

Solution Approach 1:

The patent segments the heat recovery process into multiple stages by installing steam generators at different locations between shift reactors. Each steam generator handles a specific temperature range and process requirement, allowing optimized heat recovery at each stage while maintaining manageable system complexity through modular design.

Inventive Principle:
Principle #1Segmentation

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach enhances energy efficiency by reducing steam consumption, improving syngas treatment by removing undesirable materials, and enabling the export of excess steam for power generation, thereby optimizing energy use and reducing waste in IGCC and SNG systems.

Implementation Method 1

A first steam generator is disposed along the gas path between the first and second shift reactors, wherein the first steam generator is configured to transfer heat away from the gas path to generate a first steam

Methodology Applied
Scientific EffectHeat exchange: Heat Exchanger

Implementation Method 2

an ammonia stripper configured to receive the first steam and a condensate from the gas path, wherein the ammonia stripper is configured to strip ammonia from the condensate using the first steam

Methodology Applied
Scientific EffectStripping: Distillation

Implementation Method 3

the first shift reactor is configured to perform a first shift reaction to produce a first shifted gas... the second shift reactor is configured to perform a second shift reaction to produce a second shifted gas

Methodology Applied
Scientific EffectExothermic reaction: Exothermic Reaction

Data Source

PatentUS8268266B2System for heat integration within a gas processing section
Publication Date: 2012.09.18 AIR PROD & CHEM INC
  • US8268266B2 patent drawing
  • US8268266B2 patent drawing
  • US8268266B2 patent drawing

AI summary

The present embodiments are directed towards heat integration in gas processing units. In one embodiment, a system is provided that includes a gas processing section. The gas processing section has a gas path, a first shift reactor disposed along the gas path, wherein the first shift reactor is configured to perform a first shift reaction to produce a first shifted gas. A second shift reactor is also disposed along the gas path downstream from the first shift reactor, wherein the second shift reactor is configured to perform a second shift reaction to produce a second shifted gas. A first steam generator is disposed along the gas path between the first and second shift reactors, wherein the first steam generator is configured to transfer heat away from the gas path to generate a first steam.