Heat Pump Distillation Column for High Purity Bottoms

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Solution Overview

Problem

Distillation systems in the petroleum industry are energy-intensive and inefficient, particularly when separating hydrocarbon components with similar boiling points, leading to high energy consumption and increased CO2 emissions.

Innovation Solution

The process involves using heat from overhead and intermediate vapor streams to reboil the bottoms stream in a distillation column, reducing the need for external energy by compressing these vapor streams with heat pump compressors and recycling them back into the column, thereby reducing the energy required for reboiling and improving the purity of the bottoms product.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If traditional distillation is used to separate hydrocarbons with similar boiling points, then separation can be achieved, but energy consumption is excessively high

Engineering Contradiction:
Improveseparation purityVSAvoidenergy consumption
Core Design Contradiction:
Manufacturing precisionVSUse of energy by moving object

Solution Approach 1:

The patent changes the pressure parameter of the bottoms stream by passing it through a pressure reducing valve, allowing the stream to be vaporized at lower temperatures and enabling heat exchange with overhead vapor streams, thereby reducing external energy requirements while maintaining separation purity

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent introduces an intermediary heat exchange system where the pressure-reduced bottoms stream exchanges heat with overhead vapor streams through heat exchangers, transferring thermal energy within the system to reduce the need for external heating while achieving the required separation

Inventive Principle:
Principle #24Intermediary (Mediator)

2Manufacturing precision

If more stages are added to the distillation column to improve separation, then product purity increases, but device complexity and energy consumption increase

Engineering Contradiction:
Improvebottoms product purityVSAvoidnumber of stages
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

By changing the pressure parameter of the bottoms stream and using heat pump compression, the patent achieves more efficient mass and heat transfer, reducing the number of theoretical stages needed while maintaining high bottoms product purity

Inventive Principle:
Principle #35Parameter changes

3Productivity

If external energy is added to reboil the bottoms stream, then vapor generation increases, but energy efficiency decreases

Engineering Contradiction:
Improvevapor generation rateVSAvoidexternal energy input
Core Design Contradiction:
ProductivityVSLoss of energy

Solution Approach 1:

The patent enables the distillation system to be self-sufficient by using the overhead vapor streams themselves to provide the heat needed to vaporize the bottoms stream through heat exchange, eliminating the need for external energy input while maintaining adequate vapor generation for the distillation process

Inventive Principle:
Principle #25Self-service

Solution Approach 2:

The patent uses overhead vapor streams as an intermediary heat source, transferring thermal energy from the vapor phase to the liquid bottoms stream through heat exchangers, thereby generating the required vapor without external energy addition

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach significantly decreases external energy consumption and enhances the efficiency of the distillation process, especially for mixtures with close boiling points, by reducing the number of stages needed and minimizing additional energy input, thus lowering operational costs and environmental impact.

Implementation Method 1

The vaporized bottoms stream is compressed through a heat pump compressor, thereby adding heat and bringing the stream to at least the column pressure

Methodology Applied
Scientific EffectCompression: Compression

Implementation Method 2

a portion of the bottoms liquid stream is drawn off and passed through a pressure reducing valve. This reduced pressure liquid is heat exchanged with a portion of the overhead vapor stream

Methodology Applied
Scientific EffectPressure reduction: Depressurisation

Implementation Method 3

This reduced pressure liquid is heat exchanged with a portion of the overhead vapor stream, thereby creating a vaporized bottoms stream and a condensed overhead stream

Methodology Applied
Scientific EffectHeat exchange: Heat Exchanger

Implementation Method 4

creating a vaporized bottoms stream and a condensed overhead stream

Methodology Applied
Scientific EffectCondensation: Condensation

Implementation Method 5

thereby creating a vaporized bottoms stream

Methodology Applied
Scientific EffectEvaporation: Evaporation

Implementation Method 6

Distillation is a method of separation that is based on a difference in the relative volatilities of the components in a mixture, and therefore differences in the composition between a liquid mixture and a vapor formed from the liquid mixture

Methodology Applied
Scientific EffectDistillation: Distillation

Data Source

PatentUS8182654B2Heat pump for high purity bottom product
Publication Date: 2012.05.22 UOP LLC
  • US8182654B2 patent drawing
  • US8182654B2 patent drawing
  • US8182654B2 patent drawing

AI summary

A process for reducing the energy consumption of a distillation column is disclosed. The process includes drawing off an intermediate vapor stream from the rectification section of the distillation column. The vapor stream is compressed and the heat in the vapor stream is exchanged with a portion of the liquid bottoms stream. The heat transfer condenses a portion of the vapor stream, while vaporizing the liquid bottoms stream.