Multi-Zone Heat Pump Distillation for Lower Energy Reboiling

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Solution Overview

Problem

Conventional distillation processes are inefficient in terms of energy consumption and costly due to the use of large equipment and single reboilers, which hinders widespread adoption, especially with increasing energy costs and environmental pressures.

Innovation Solution

An improved distillation apparatus with a folded column design incorporating multiple heat pumps and reboiler heat exchangers, allowing for energy-efficient separation zones with separate overhead and stripping loops, reducing capital costs and energy consumption.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of manufacture

If conventional distillation systems employ a single reboiler at the bottom stage, then capital cost is reduced, but energy efficiency deteriorates

Engineering Contradiction:
Improvecapital costVSAvoidenergy efficiency
Core Design Contradiction:
Ease of manufactureVSUse of energy by moving object

Solution Approach 1:

The distillation column is divided into multiple sections, each equipped with its own reboiler. This segmentation allows independent optimization of energy usage in different column sections, enabling better overall energy efficiency while distributing capital investment across multiple smaller, modular units rather than one large expensive reboiler.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

Heat exchangers are nested within the column structure itself, with reboilers positioned at multiple levels inside the column. This nesting integrates the heating functions directly into the separation process, reducing energy losses and improving thermal efficiency without requiring external equipment that would increase capital costs.

Inventive Principle:
Principle #7Nested doll (Nesting)

2Use of energy by moving object

If multiple reboilers are added to conventional distillation columns, then energy efficiency is improved, but capital cost increases

Engineering Contradiction:
Improveenergy efficiencyVSAvoidcapital cost
Core Design Contradiction:
Use of energy by moving objectVSEase of manufacture

Solution Approach 1:

Multiple reboiler functions are merged into a integrated column design where heat exchangers at different levels work together as a coordinated system. The waste heat from upper sections is utilized by lower sections, creating a cascading heat recovery system that achieves high energy efficiency without proportionally increasing capital costs.

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The reboiler units are designed to serve multiple functions: they provide localized heating for separation, act as heat exchangers for energy recovery, and contribute to the overall structural integrity of the column. This multi-functionality reduces the need for separate dedicated equipment, thereby controlling capital costs while maintaining energy efficiency.

Inventive Principle:
Principle #6Universality (Multi-functionality)

3Manufacturing precision

If the number of plates or trays is increased, then separation performance is improved, but equipment size and cost increase

Engineering Contradiction:
Improveseparation performanceVSAvoidequipment size
Core Design Contradiction:
Manufacturing precisionVSVolume of stationary object

Solution Approach 1:

Rather than uniformly increasing the number of plates throughout the entire column, the invention applies enhanced separation functionality only in specific zones where it is most needed. Multiple reboilers are strategically positioned at key locations to provide localized intensive heating and separation, achieving high overall separation performance with fewer total plates and smaller equipment volume.

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution significantly reduces energy consumption and capital costs by optimizing the column design, enabling more efficient separation and product recovery while minimizing equipment size and environmental impact.

Implementation Method 1

The vapor is compressed in a heat pump to a temperature and pressure sufficient to heat the liquid in the stripping section

Methodology Applied
Scientific EffectCompression: Compression

Implementation Method 2

The vapor from the rectification section is compressed in a heat pump

Methodology Applied
Scientific EffectHeat pump: Pump

Implementation Method 3

The compressed vapor is then passed through a heat exchanger to heat the liquid in the stripping section

Methodology Applied
Scientific EffectHeat exchange: Heat Exchanger

Implementation Method 4

The vapor is then condensed and any uncondensed vapor is recycled to the column top

Methodology Applied
Scientific EffectCondensation: Condensation

Implementation Method 5

Distillation is a method of separation that is based on a difference in composition between a liquid mixture and a vapor formed from the liquid mixture

Methodology Applied
Scientific EffectDistillation: Distillation

Implementation Method 6

Distillation normally involves partial or flash vaporization of the liquid composition followed by condensation of the vaporized material

Methodology Applied
Scientific EffectVaporization: Evaporation

Data Source

PatentUS8273219B2Heat pump distillation
Publication Date: 2012.09.25 UOP LLC
  • US8273219B2 patent drawing
  • US8273219B2 patent drawing

AI summary

A distillation column is disclosed. The column includes a plurality of rectification zones and corresponding stripping zones. Each rectification zone is linked to a heat pump or a stage of a heat pump. Overhead material from the top rectification zone is compressed and used to heat bottoms liquid from the bottom stripping zone. Similarly, overhead material from a lower rectification zone is compressed and used to heat liquid taken from the uppermost or top stripping zone. Optionally, overhead material from a middle rectification zone is compressed and used to heat liquid from a middle stripping zone. A single multiple stage heat pump compressor may be utilized as opposed to a plurality of heat pumps. Because the heat exchanger from each rectification-stripping zone pair has a lower duty, economical stab-in heat exchangers may be utilized.