Heat Pump Fractionation Column with Auxiliary Reboiler

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Solution Overview

Problem

Existing heat pump systems face challenges in ensuring reliable operation when handling compounds with high boiling points and molecular weights, as they often risk sending liquid to the compressor, leading to potential damage and prolonged shutdowns, especially in applications like separating xylenes, benzene, or C9+ hydrocarbons.

Innovation Solution

The system employs an auxiliary reboiler to maintain column operation during compressor shutdowns, using an inert non-condensable gas to warm the heat pump loop, allowing the compressor to be isolated and restarted without interrupting the distillation process, and routing vapors directly to the receiver to prevent condensation and compressor damage.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Adaptability or versatility

If a heat pump system is used with high boiling point compounds, then the separation capability is improved, but the risk of liquid entering the compressor increases

Engineering Contradiction:
Improveseparation capabilityVSAvoidcompressor operation reliability
Core Design Contradiction:
Adaptability or versatilityVSReliability

Solution Approach 1:

The patent implements a pre-heating system that warms the heat pump compressor and associated piping before admitting high boiling point compounds. This preliminary action ensures the system is at the required temperature to prevent condensation and liquid formation in the compressor, thereby maintaining reliability while enabling the use of high boiling point compounds for separation

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent introduces a liquid knockout drum as an intermediary device between the distillation column and the heat pump compressor. This drum removes entrained liquid droplets from the vapor stream before it enters the compressor, preventing liquid damage while allowing the heat pump to continue operating with high boiling point compounds

Inventive Principle:
Principle #24Intermediary (Mediator)

2Device complexity

If a single drum is used for both receiver and knockout functions, then the device complexity is reduced, but the reliability during startup decreases

Engineering Contradiction:
Improvedrum configurationVSAvoidstartup reliability
Core Design Contradiction:
Device complexityVSReliability

Solution Approach 1:

The patent divides the single combined drum into two separate functional units: a liquid knockout drum and a vapor receiver. This segmentation allows the knockout drum to specifically handle liquid removal during startup and operation, while the receiver handles vapor condensation, thereby improving startup reliability without significantly increasing overall system complexity

Inventive Principle:
Principle #1Segmentation

3Reliability

If the heat pump compressor is shutdown to prevent liquid damage, then the compressor reliability is protected, but the production interruption increases

Engineering Contradiction:
Improvecompressor protectionVSAvoidproduction continuity
Core Design Contradiction:
ReliabilityVSProductivity

Solution Approach 1:

The patent implements pre-heating and liquid knockout procedures before starting the heat pump compressor with high boiling point compounds. This preliminary preparation prevents liquid damage from occurring in the first place, allowing the compressor to run continuously without shutdowns for protection, thereby maintaining production continuity while protecting compressor reliability

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The liquid knockout drum acts as an intermediary that protects the compressor from liquid damage during normal operation. By removing liquid droplets before they reach the compressor, the system avoids emergency shutdowns and can maintain continuous operation, preserving productivity while ensuring compressor protection

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This configuration ensures high on-stream reliability, minimizes production interruptions, and reduces the need for external heat sources by using electrical energy for separation, allowing for quick restarts and continuous operation even during compressor downtime.

Implementation Method 1

The auxiliary reboiler is used to provide thermal energy to the distillation column

Methodology Applied
Scientific EffectThermal energy transfer: Heating

Implementation Method 2

introducing an inert non-condensable gas into a loop comprising the isolated suction drum and the heat pump to raise a temperature of the loop

Methodology Applied
Scientific EffectConvection heat transfer: Convection

Implementation Method 3

sending the overhead vapor product stream from the distillation column directly to the receiver; sending a vapor stream from the suction drum to the heat pump, wherein the vapor stream remains in the vapor phase in the heat pump

Methodology Applied
Scientific EffectGas compression: Compression

Implementation Method 4

the condensing medium is typically admitted to the column as a vapor

Methodology Applied
Scientific EffectCondensation: Condensation

Implementation Method 5

separating a high boiling point liquid feed stream comprising in the distillation column into an overhead product vapor stream and a liquid bottom stream

Methodology Applied
Scientific EffectFractional distillation: Distillation

Data Source

PatentUS10688407B1Fractionation column with heat pump using high boiling point vapor
Publication Date: 2020.06.23 UOP LLC
  • US10688407B1 patent drawing

AI summary

Process and apparatus ensure high on-stream reliability of a complex that requires a heat pump which is using a compound having a high boiling point, such as xylenes. When the compressor is shutdown, it can be isolated from the distillation column and receiver while the column is allowed to continue to operate with an auxiliary reboiler for constant heat input. The heat pump can be started up and heated to the normal process temperature, so that when the heavy vapor is charged to the heat pump, it does not immediately condense into liquid, causing damage to the compressor.