Heat Resistant Slipping Layer for Thermal Transfer Sheets

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Solution Overview

Problem

Thermal transfer sheets face issues with dye retransfer from the color material layer to the heat resistant slipping layer, leading to printing precision impairments, especially when stored in a wound state and during rewinding, due to increased heat energy and sensitivity of ink ribbons.

Innovation Solution

A thermal transfer sheet with a heat resistant slipping layer comprising a cellulose acetate butyrate resin with a butyryl group content of 50% or higher and a lubricant, along with additional resins like acrylic or polyvinyl acetal, which reduces dye retransfer and maintains excellent heat resistance and slip properties.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of operation

If the thermal transfer sheet is stored in a wound state after printing, then the sheet can be conveniently stored and transported, but the color material layer is pressed against the heat resistant slipping layer causing dye transfer and retransfer that impairs printing precision

Engineering Contradiction:
Improvestorage convenienceVSAvoidprinting precision
Core Design Contradiction:
Ease of operationVSManufacturing precision

Solution Approach 1:

A release layer is introduced between the color material layer and the heat resistant slipping layer to prevent direct contact and dye transfer during wound-state storage. The release layer acts as an intermediary barrier that eliminates the harmful interaction while allowing the sheet to maintain its wound storage form.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The harmful direct contact between the color material layer and heat resistant slipping layer is eliminated by separating them with a release layer. This extraction of the problematic interaction prevents dye transfer while preserving the beneficial wound storage capability.

Inventive Principle:
Principle #2Taking out (Extraction)

2Productivity

If heat energy of the thermal head is increased to speed up printing, then printing speed is improved, but the possibility of transferring dye from the color material layer to the heat resistant slipping layer increases

Engineering Contradiction:
Improveprinting speedVSAvoiddye transfer
Core Design Contradiction:
ProductivityVSObject-generated harmful factors

Solution Approach 1:

The release layer serves as a protective intermediary that prevents dye transfer to the heat resistant slipping layer even when high heat energy is applied during printing. This intermediary barrier allows high-speed printing with increased thermal head energy without the harmful side effect of dye contamination.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The release layer is pre-applied to the heat resistant slipping layer before printing occurs, providing beforehand protection against dye transfer. This prior cushioning measure ensures that even when high heat energy is subsequently applied for fast printing, the dye cannot transfer to the slipping layer.

Inventive Principle:
Principle #11Beforehand cushioning (Prior cushioning)

3Manufacturing precision

If a transfer protective layer is provided to avoid impairing image characteristics, then image quality is improved, but the transparent film allows dye retransfer to occur and emphasizes contamination

Engineering Contradiction:
Improveimage qualityVSAvoiddye retransfer
Core Design Contradiction:
Manufacturing precisionVSObject-generated harmful factors

Solution Approach 1:

The release layer is positioned between the color material layer and the transfer protective layer to prevent dye retransfer to the transparent film. This intermediary barrier maintains the transparency and image quality benefits of the protective layer while eliminating the harmful retransfer effect.

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution effectively minimizes dye retransfer, maintains printing precision, and ensures stable color reproduction even after storage, by optimizing the composition of the heat resistant slipping layer with specific resin content and lubricants.

Implementation Method 1

a heat resistant slipping layer which contains a binder resin containing a cellulose acetate butyrate resin (A1) having a butyryl group content of 50% or higher and a lubricant (B)

Methodology Applied
Scientific EffectAdhesion: Adhesive

Implementation Method 2

the heat resistant slipping layer includes a binder resin containing a cellulose acetate butyrate resin (A1) having a butyryl group content of 50% or higher and a lubricant (B)

Methodology Applied
Scientific EffectLubrication: Lubrication

Implementation Method 3

a sublimation dye transfer ink layer composed of a sublimation dye and a binder is provided on one surface of a base film as a color material layer

Methodology Applied
Scientific EffectThermal conduction: Conduction (thermal)

Implementation Method 4

a sublimation dye transfer ink layer composed of a sublimation dye and a binder

Methodology Applied
Scientific EffectSublimation: Sublimation

Implementation Method 5

a thermofusible transfer ink layer composed of a pigment and a wax

Methodology Applied
Scientific EffectMelting: Melting

Data Source

PatentEP2067630B1Heat transfer sheet
Publication Date: 2013.03.27 DAI NIPPON PRINTING CO LTD
  • EP2067630B1 patent drawing
  • EP2067630B1 patent drawing
  • EP2067630B1 patent drawing

AI summary

It is an object of the present invention to provide a thermal transfer sheet provided with a heat resistant slipping layer which reduces dye retransfer, has excellent heat resistance and slip properties, and prevents the defects of printed image from being generated due to wrinkles and the like during printing. A thermal transfer sheet comprising a base film, a color material layer on one surface of the base film, and a heat resistant slipping layer on the other surface of the base film, wherein the heat resistant slipping layer comprises a binder resin containing a cellulose acetate butyrate resin (A1) having a butyryl group content of 50% or more and a lubricant (B), the amount of the binder resin is 65 to 99% by weight of the total solid content of the heat resistant slipping layer, the amount of the cellulose acetate butyrate resin (A1) is 50 to 100% by weight of the binder resin, and the amount of the lubricant (B) is 1 to 30% by weight of the binder resin.