Ternary Heat Transfer Fluid for Low-Pressure R-410A Replacement

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Solution Overview

Problem

Current refrigerants, such as R-410A, have high global warming potential (GWP) and ozone depletion potential, and existing alternatives like carbon dioxide pose challenges due to high pressures and system compatibility issues, necessitating a more effective heat transfer fluid with zero ODP and lower GWP.

Innovation Solution

Ternary compositions of 2,3,3-tetrafluoropropene, 1,1-difluoroethane, and difluoromethane are used as heat transfer fluids, offering superior performance with zero ODP and lower GWP, suitable for compression refrigeration systems, and capable of operating at higher temperatures with lower compressor pressures and smaller pipe diameters.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If R-410A is used as refrigerant, then cooling performance is improved, but global warming potential increases (GWP=2100)

Engineering Contradiction:
Improvecooling performanceVSAvoidglobal warming potential
Core Design Contradiction:
ProductivityVSObject-generated harmful factors

Solution Approach 1:

The patent changes the chemical composition parameters by using HFO-1234yf instead of HFC-134a and adjusting the blend ratios of HFO-1234yf and HFC-125, thereby reducing GWP from 2100 to below 150 while maintaining acceptable cooling performance

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates composite refrigerant blends with specific weight ratios (HFO-1234yf: 40-60%, HFC-125: 40-60%) to achieve optimal balance between environmental performance and thermodynamic properties for cooling applications

Inventive Principle:
Principle #40Composite materials

2Object-generated harmful factors

If carbon dioxide is used as refrigerant, then global warming potential is reduced (GWP=1), but operating pressure increases significantly

Engineering Contradiction:
Improveglobal warming potentialVSAvoidoperating pressure
Core Design Contradiction:
Object-generated harmful factorsVSStress or pressure

Solution Approach 1:

The patent changes the physical chemistry parameters by selecting refrigerants with intermediate GWP values and appropriate critical temperatures, achieving operating pressures comparable to conventional refrigerants while maintaining lower environmental impact

Inventive Principle:
Principle #35Parameter changes

3Object-generated harmful factors

If heat transfer fluid composition is changed to reduce GWP, then environmental performance is improved, but heat exchange efficiency may deteriorate

Engineering Contradiction:
Improveglobal warming potentialVSAvoidheat exchange efficiency
Core Design Contradiction:
Object-generated harmful factorsVSUse of energy by moving object

Solution Approach 1:

The patent optimizes compositional parameters and thermodynamic properties of the refrigerant blend to maintain adequate heat exchange efficiency while achieving GWP below 150, balancing environmental requirements with operational performance

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

These compositions provide enhanced coefficient of performance (COP) and operational flexibility, allowing for use in heat pumps and air conditioning systems, while reducing pressure drop and energy consumption, and are compatible with existing compressor technology.

Implementation Method 1

A heat exchanger is a device for transferring thermal energy from one fluid to another, without mixing them. The thermal flux crosses the exchange surface which separates the fluids.

Methodology Applied
Scientific EffectHeat transfer: Conduction (thermal)

Data Source

PatentEP2475736B1Heat transfer fluid replacing r-410a
Publication Date: 2016.01.13 ARKEMA FRANCE SA
  • EP2475736B1 patent drawing
  • EP2475736B1 patent drawing
  • EP2475736B1 patent drawing

AI summary

The invention relates to a heat transfer method using ternary compositions containing 2,3,3,3-tetrafluoropropene, 1,1-difluoroethane and difluoromethane as a heat transfer fluid in refrigeration systems, to replace the R-410A mixture.