Heated Porous Inlet for Real-Time Mobile Chemical Sampling

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Solution Overview

Problem

Existing chemical detection systems face challenges in collecting and delivering samples from surfaces, particularly in real-time and mobile applications, as they often fail to effectively handle vapor, liquid, and solid samples, and are prone to false positives due to selective sampling methods.

Innovation Solution

A sampling device with a heated porous metal inlet and transfer line that allows for real-time collection and delivery of vapor, liquid, and solid samples, using air jets to agitate surfaces and prevent direct contact, while maintaining high flow rates and preventing particulate matter from entering the system.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Quantity of substance

If a permeation membrane is used for sample enrichment, then compound enrichment is achieved, but response time and recovery are reduced

Engineering Contradiction:
Improvecompound enrichmentVSAvoidresponse time
Core Design Contradiction:
Quantity of substanceVSSpeed

Solution Approach 1:

The patent uses a heated porous inlet (porous frit) instead of a permeation membrane. The porous structure allows direct physical contact and adsorption of compounds onto the inlet surface, enabling rapid sample uptake without the selective permeation limitations that slow down membrane-based systems. This resolves the contradiction by achieving both enrichment and fast response through porous material physics rather than selective diffusion.

Inventive Principle:
Principle #31Porous materials

2Quantity of substance

If selective permeation is used for sample enrichment, then compound enrichment is achieved, but some compounds are selectively suppressed

Engineering Contradiction:
Improvecompound enrichmentVSAvoidcompound detection range
Core Design Contradiction:
Quantity of substanceVSAdaptability or versatility

Solution Approach 1:

The porous frit inlet provides non-selective physical adsorption based on surface area and porosity, rather than molecular-size-based selective permeation. This allows a broad range of compounds (volatile, semi-volatile, and condensed phases) to be enriched equally without selective suppression, resolving the contradiction between enrichment and versatility.

Inventive Principle:
Principle #31Porous materials

Solution Approach 2:

The system uses heating of the porous inlet to change the physical state of samples (vaporization of liquids and solids), enabling detection of compounds in various phases. This parameter change (temperature) allows universal sample enrichment across different compound types without selective suppression.

Inventive Principle:
Principle #35Parameter changes

3Speed

If real-time detection is implemented in mobile applications, then detection speed is improved, but sampling reliability in diverse environments deteriorates

Engineering Contradiction:
Improvedetection speedVSAvoidsampling reliability
Core Design Contradiction:
SpeedVSReliability

Solution Approach 1:

The heated porous inlet design is universally applicable to sampling various compound types (gases, vapors, liquids, solids) in diverse environments. The non-selective porous structure and heating capability provide reliable sample collection across different media and conditions, maintaining sampling reliability while enabling real-time mobile detection.

Inventive Principle:
Principle #6Universality (Multi-functionality)

Solution Approach 2:

The system utilizes phase transitions (vaporization of liquids and solids on the heated porous inlet) to convert various sample phases into vapor form for detector analysis. This phase change mechanism ensures reliable sampling of diverse compounds regardless of their initial physical state, maintaining reliability in mobile real-time applications.

Inventive Principle:
Principle #36Phase transitions

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

Enables efficient, real-time sampling and analysis of toxic and hazardous compounds in hazardous environments, minimizing cycle time and carryover effects, and operating effectively in motion, with reduced false positives and improved response times compared to membrane-based systems.

Implementation Method 1

For trace chemical analyzers, the liquid and solid sample must be vaporized

Methodology Applied
Scientific EffectVaporization: Evaporation

Implementation Method 2

a permeation membrane that is heated for delivery to a detector

Methodology Applied
Scientific EffectPermeation: Permeation

Data Source

PatentUS8402842B2Surface sampling mobile chemical detection probe
Publication Date: 2013.03.26 RAPISCAN SYST INC (US)
  • US8402842B2 patent drawing
  • US8402842B2 patent drawing
  • US8402842B2 patent drawing

AI summary

A sampling device that contains a heated porous inlet and a transfer line. The device provides sample compounds present as vapor, liquid, or solid, in air, or on surfaces such as soil. The sample device can collect and deliver the sample to an analyzer in real time and can operate while in motion such as on a moving vehicle. The sampling device is especially useful to screen toxic and hazardous compounds that might be contaminating an inhabited area.