Heavy Metal Capture Composition for Perovskite Solar Cells

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Solution Overview

Problem

Electronic devices such as LEDs and solar cells that utilize heavy metals like cadmium, lead, and cesium are prone to environmental degradation and leaching, leading to contamination, and existing solutions fail to effectively capture and contain these metals, posing a risk to the environment.

Innovation Solution

A heavy metal capture composition comprising a matrix material and an ion exchangeable material, which can include phosphate, tungstate, molybdate, sulfate, or silicate, is used to bind and trap heavy metals, reducing their leaching into the environment by forming a flocculate or precipitate, and is applied as a layer or coating on devices to prevent contamination.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If heavy metals are used in electronic devices, then device performance and cost are improved, but environmental degradation and leaching occur

Engineering Contradiction:
Improvedevice performanceVSAvoidenvironmental degradation
Core Design Contradiction:
ProductivityVSObject-affected harmful factors

Solution Approach 1:

An ion exchangeable material is introduced as an intermediary between the heavy metal-containing active material and the environment. This material captures and binds heavy metal ions that leach from the active material, preventing their release into the environment while allowing the active material to maintain its functional performance.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The ion exchangeable material is applied as a thin film or coating layer on or near the heavy metal-containing active material. This thin film structure provides effective heavy metal capture without adding significant bulk or complexity to the device, maintaining device performance while preventing environmental contamination.

Inventive Principle:
Principle #30Flexible shells and thin films

2Object-affected harmful factors

If ion exchangeable material is added to capture heavy metals, then heavy metal leaching is reduced, but device complexity increases

Engineering Contradiction:
Improveheavy metal leachingVSAvoiddevice complexity
Core Design Contradiction:
Object-affected harmful factorsVSDevice complexity

Solution Approach 1:

The ion exchangeable material is applied as a thin film or coating rather than a bulk material, minimizing the additional structural complexity. The thin film can be deposited using standard coating techniques and integrated into existing device architectures without requiring fundamental redesign.

Inventive Principle:
Principle #30Flexible shells and thin films

Solution Approach 2:

The ion exchangeable material serves multiple functions: it captures heavy metal ions, provides a barrier to leaching, and can be applied as a coating that integrates with existing device structures. This multi-functionality reduces the need for additional separate components, thereby limiting the increase in device complexity.

Inventive Principle:
Principle #6Universality (Multi-functionality)

3Object-affected harmful factors

If ion exchangeable material is used to bind heavy metals, then heavy metal leaching is reduced, but manufacturing complexity increases

Engineering Contradiction:
Improveheavy metal leachingVSAvoidmanufacturing complexity
Core Design Contradiction:
Object-affected harmful factorsVSEase of manufacture

Solution Approach 1:

The thin film application of ion exchangeable material can be deposited using standard coating techniques such as spin coating, dip coating, or spray coating, which are compatible with existing manufacturing processes. This approach avoids the need for complex assembly steps or specialized manufacturing equipment.

Inventive Principle:
Principle #30Flexible shells and thin films

Solution Approach 2:

The ion exchangeable material can be applied in various forms (powders, solutions, suspensions) and processed under different conditions (temperature, humidity, drying time). This flexibility in processing parameters allows integration into existing manufacturing workflows without requiring significant process changes.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The composition significantly reduces heavy metal leaching by up to 99% and captures lead from perovskite solar cells below regulatory limits, demonstrating robustness against physical and chemical degradation, and facilitates recycling of captured metals.

Implementation Method 1

an ion exchangeable material. The ion exchangeable material binds to the heavy metal to reduce an amount of heavy metal in the environment

Methodology Applied
Scientific EffectIon exchange: Ion Exchange

Implementation Method 2

the ion exchangeable material traps the heavy metal in the composition, or forms a flocculate or a precipitate with the heavy metal

Methodology Applied
Scientific EffectPrecipitation: Precipitation

Implementation Method 3

the matrix material can include an organic or inorganic polymer including one or more complexing moieties

Methodology Applied
Scientific EffectComplexation: Chemical Bonding

Data Source

PatentUS20220135442A1Thin-films for capturing heavy metal
Publication Date: 2022.05.05 MASSACHUSETTS INST OF TECH
  • US20220135442A1 patent drawing
  • US20220135442A1 patent drawing
  • US20220135442A1 patent drawing

AI summary

A heavy metal capture composition, devices including the composition, and a method of reducing heavy metal contamination in the environment is described.