Heteroaromatic Electron-Transport Layer for OLED Heat Resistance

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

Conventional light-emitting devices face challenges in achieving high heat resistance and reliability, particularly during the manufacturing process, while also requiring low power consumption and efficient performance.

Innovation Solution

The light-emitting device incorporates a structure with a heteroaromatic compound-based second electron-transport layer, an insulating layer, and an electron-injection layer, which enhances heat resistance and reliability by inhibiting crystallization and allowing high-temperature processing, and includes a heteroaromatic ring such as quinoline or benzoquinoline, combined with an organic compound to improve electron-transport properties.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional electron-transport layers are used in light-emitting devices, then the device structure is simple, but the heat resistance and reliability are insufficient

Engineering Contradiction:
Improveheat resistance and reliabilityVSAvoidlayer structure complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The electron-transport function is segmented into two distinct layers: a first electron-transport layer adjacent to the light-emitting layer, and a second electron-transport layer adjacent to the first electron-transport layer. This segmentation allows each layer to be optimized for specific functions, with the second layer providing heat resistance through heteroaromatic compounds while the first layer handles electron transport, thereby resolving the contradiction between reliability improvement and structural complexity.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The second electron-transport layer employs composite materials containing heteroaromatic compounds (such as quinoline or benzoquinoline derivatives) combined with other organic compounds. This composite approach enhances heat resistance and reliability through the unique molecular structure and thermal stability of heteroaromatic compounds, while maintaining electron-transport capability, thus improving reliability without excessive complexity increase.

Inventive Principle:
Principle #40Composite materials

2Productivity

If high-temperature processing is performed to improve manufacturing, then productivity increases, but crystallization occurs in conventional organic layers

Engineering Contradiction:
Improvemanufacturing efficiencyVSAvoidcrystallization resistance
Core Design Contradiction:
ProductivityVSStability of the object's composition

Solution Approach 1:

The second electron-transport layer uses heteroaromatic compounds with specific molecular structures that have high glass transition temperatures and resistance to crystallization. This parameter change in material selection enables the layer to withstand high-temperature processing conditions without crystallizing, allowing manufacturers to perform high-temperature steps to improve productivity while maintaining composition stability through the inherent thermal properties of heteroaromatic structures.

Inventive Principle:
Principle #35Parameter changes

3Use of energy by moving object

If power consumption is reduced, then energy efficiency improves, but performance and reliability may deteriorate

Engineering Contradiction:
Improvepower consumptionVSAvoiddevice performance and reliability
Core Design Contradiction:
Use of energy by moving objectVSReliability

Solution Approach 1:

The second electron-transport layer acts as an intermediary between the first electron-transport layer and the electrode, providing a stable, high heat-resistance foundation that protects the light-emitting layer from thermal degradation. This intermediary structure enables low power consumption operation by preventing energy loss through thermal runaway and material degradation, thereby maintaining reliability and performance even at reduced power levels through improved thermal management.

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This configuration results in a light-emitting device with improved heat resistance, reliability, and low power consumption, enabling efficient performance and extended lifespan.

Implementation Method 1

enhances heat resistance and reliability by inhibiting crystallization and allowing high-temperature processing

Methodology Applied
Scientific EffectCrystallization inhibition:

Implementation Method 2

the second electron-transport layer contains a heteroaromatic compound including at least one heteroaromatic ring and an organic compound different from the heteroaromatic compound

Methodology Applied
Scientific EffectElectron transport: Conduction (electrical)

Implementation Method 3

Light-emitting devices (organic EL devices) including organic compounds and utilizing electroluminescence (EL) have been put to more practical use. Carriers are injected by application of voltage to the element, and recombination energy of the carriers is used, whereby light emission can be obtained from the light-emitting material

Methodology Applied
Scientific EffectElectroluminescence: Electroluminescence

Data Source

PatentUS20240121979A1Light-Emitting Device, Light-Emitting Apparatus, Electronic Appliance, and Lighting Device
Publication Date: 2024.04.11 SEMICON ENERGY LAB CO LTD
  • US20240121979A1 patent drawing
  • US20240121979A1 patent drawing
  • US20240121979A1 patent drawing

AI summary

A light-emitting device with high heat resistance in a manufacturing process is to be provided. The light-emitting device includes a second electrode over a first electrode with an EL layer sandwiched therebetween; the EL layer includes at least a light-emitting layer, a first electron-transport layer, a second electron-transport layer, and an electron-injection layer; the first electron-transport layer is over the light-emitting layer; the second electron-transport layer is over the first electron-transport layer; the light-emitting device includes an insulating layer in contact with a side surface of the light-emitting layer, a side surface of the first electron-transport layer, and a side surface of the second electron-transport layer; the electron-injection layer is over the second electron-transport layer; the insulating layer is positioned between the electron-injection layer and the side surface of the light-emitting layer, the side surface of the first electron-transport layer, and the side surface of the second electron-transport layer; and the second electron-transport layer contains a heteroaromatic compound including at least one heteroaromatic ring and an organic compound different from the heteroaromatic compound.