Heteroaromatic Matrix Compounds for OLED Voltage and Lifetime

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Solution Overview

Problem

Organic electroluminescent devices face challenges in achieving high lifetime, efficiency, and low operating voltage, particularly due to limitations in matrix materials used, which also affect color purity and temperature stability.

Innovation Solution

Development of specific compounds with a defined structure, such as those described in formula (I), which are used as matrix materials or electron transport materials to enhance the performance of organic electroluminescent devices, including red- and green-phosphorescing devices, by improving their efficiency, lifetime, and operating voltage.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Duration of action of stationary object

If conventional matrix materials are used in phosphorescent OLEDs, then device fabrication is straightforward, but device lifetime is short and efficiency is limited

Engineering Contradiction:
Improvedevice lifetimeVSAvoidmaterial selection complexity
Core Design Contradiction:
Duration of action of stationary objectVSEase of manufacture

Solution Approach 1:

The patent employs composite materials by combining specific heteroaromatic ring systems (triazine, pyrimidine, pyrazine) with various substituents to create matrix materials with optimized properties. This composite approach allows simultaneous improvement of device lifetime, efficiency, and color purity while maintaining processability through controlled molecular structure design

Inventive Principle:
Principle #40Composite materials

2Manufacturing precision

If existing matrix materials are used, then device structure is simple, but color purity is insufficient

Engineering Contradiction:
Improvecolor purityVSAvoidmaterial structure complexity
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The patent applies local quality by introducing specific functional groups and heteroaromatic ring systems at particular positions within the molecular structure to optimize color purity. The localized placement of nitrogen-containing rings and substituents allows precise control over emission characteristics while maintaining overall material processability

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The patent utilizes parameter changes by systematically varying molecular weight, substituent types, and ring system configurations to optimize color purity. By adjusting these molecular parameters within defined ranges, the invention achieves enhanced color purity without excessive structural complexity

Inventive Principle:
Principle #35Parameter changes

3Use of energy by stationary object

If standard matrix materials are employed, then operating voltage is high, but material synthesis is simpler

Engineering Contradiction:
Improveoperating voltageVSAvoidsynthesis complexity
Core Design Contradiction:
Use of energy by stationary objectVSEase of manufacture

Solution Approach 1:

The patent applies parameter changes by optimizing molecular structure parameters (ring system type, substituent groups, molecular weight) to reduce operating voltage. These controlled parameter variations within the compound class enable lower operating voltages while maintaining reasonable synthesis complexity through established organic synthesis methods

Inventive Principle:
Principle #35Parameter changes

4Productivity

If conventional materials are used, then device performance is adequate, but efficiency is suboptimal

Engineering Contradiction:
Improvedevice efficiencyVSAvoidperformance consistency
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The patent employs composite materials with specific heteroaromatic core structures and tailored substituents to enhance device efficiency. This composite design, featuring nitrogen-containing rings combined with electron-donating or electron-withdrawing groups, improves charge transport and recombination efficiency while maintaining performance consistency across devices

Inventive Principle:
Principle #40Composite materials

Data Source

PatentUS20240188429A1Compounds for organic electroluminescent devices
Publication Date: 2024.06.06 MERCK PATENT GMBH
  • US20240188429A1 patent drawing
  • US20240188429A1 patent drawing
  • US20240188429A1 patent drawing

AI summary

The present invention relates to compounds that are suitable for use in electronic devices, and to electronic devices, more particularly organic electroluminescent devices, containing these compounds.