Heterocyclic Amine Compound for OLED Efficiency and Lifetime

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Solution Overview

Problem

There is a need for novel organic light-emitting materials that exhibit high luminance, light emission efficiency, and longevity for organic light-emitting diodes (OLEDs) to surpass conventional technologies.

Innovation Solution

The development of a heterocyclic amine compound represented by specific chemical formulas, which are used in the light-emitting layer of OLEDs, enhancing luminance and light emission efficiency while ensuring a long lifetime.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Device complexity

If a single material is employed as the luminescent material, then the device structure is simple, but intermolecular actions cause the maximum luminescence wavelength to shift toward a longer wavelength, resulting in a reduction in color purity and light emission efficiency

Engineering Contradiction:
Improvedevice structureVSAvoidlight emission efficiency
Core Design Contradiction:
Device complexityVSLoss of energy

Solution Approach 1:

The luminescent material is divided into two separate components: a host material and a dopant material. The host material provides the structural framework and general luminescence properties, while the dopant material is added in small amounts (0.01-20 wt%) to achieve the desired color and enhance light emission efficiency without causing significant wavelength shifts. This segmentation resolves the contradiction by maintaining simple device structure while improving light emission efficiency through the synergistic combination of host and dopant materials.

Inventive Principle:
Principle #1Segmentation

2Loss of energy

If a dopant is added to the host material to increase color purity and light emission efficiency, then light emission efficiency is improved, but the device complexity increases

Engineering Contradiction:
Improvelight emission efficiencyVSAvoiddevice structure
Core Design Contradiction:
Loss of energyVSDevice complexity

Solution Approach 1:

The host material serves multiple functions simultaneously: it provides the structural framework for the luminescent layer, generates excitons through energy transfer, and enables the dopant to emit light at the desired wavelength. The dopant, in turn, provides both color tuning and efficiency enhancement. This multi-functionality approach allows the system to achieve improved light emission efficiency without proportionally increasing device complexity, as the same components perform multiple roles.

Inventive Principle:
Principle #6Universality (Multi-functionality)

3Ease of manufacture

If conventional luminescent materials are used in OLEDs, then the device can be manufactured with existing technology, but the luminance, light emission efficiency, and lifetime are insufficient to surpass conventional technologies

Engineering Contradiction:
ImprovemanufacturabilityVSAvoidlifetime
Core Design Contradiction:
Ease of manufactureVSReliability

Solution Approach 1:

The invention changes the chemical and physical parameters of the luminescent materials by selecting specific host and dopant combinations with optimized energy levels, molecular weights, and structural properties. The host material is chosen to have appropriate triplet energy levels and good charge transport properties, while the dopant is selected to match the desired emission wavelength and provide high quantum efficiency. These parameter optimizations enable the OLED to achieve superior lifetime and performance while remaining compatible with existing manufacturing processes.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The amine compound significantly improves luminance, light emission efficiency, and longevity of OLEDs, demonstrating higher performance compared to conventional materials.

Implementation Method 1

An organic light-emitting device using the organic light-emitting phenomenon has a structure usually comprising an anode, a cathode, and an organic material layer interposed therebetween... when a voltage is applied between the two electrodes, a hole injected from the anode migrates to the organic layer while an electron is released from the cathode and moves toward the organic layer. In the luminescent zone, the hole and the electron recombine to produce an exciton. When the exciton returns to the ground state from the excited state, the molecule of the organic layer emits light.

Methodology Applied
Scientific EffectElectroluminescence: Electroluminescence

Data Source

PatentUS11672172B2Heterocyclic compound comprising aromatic amine group and organic light-emitting diode including the same
Publication Date: 2023.06.06 SFC CO LTD
  • US11672172B2 patent drawing
  • US11672172B2 patent drawing
  • US11672172B2 patent drawing

AI summary

The present invention relates to a heterocyclic compound containing an aromatic amine group and an organic light-emitting device comprising the same and, more specifically, to a heterocyclic compound and an organic light-emitting device comprising the same, the heterocyclic compound being excellent in brightness and excellent light emission efficiency and being able to exhibit long life and excellent device characteristics when being used as an organic light-emitting material.