Heterocyclic Compound Emission Layers for Blue Light Luminance

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Solution Overview

Problem

Existing light-emitting devices face challenges in achieving high luminance, efficient energy use, and long lifespan, particularly in blue light emission, due to limitations in the materials used in the emission layer.

Innovation Solution

Incorporation of a heterocyclic compound represented by Formula 1 in the emission layer, which can include a transition metal-containing compound and a delayed fluorescence compound, along with a second compound featuring a π electron-deficient nitrogen-containing C1-C60 heterocyclic group, to enhance light emission properties.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Illumination intensity

If conventional materials are used in the emission layer, then the device structure is simple, but the luminance and energy efficiency are insufficient

Engineering Contradiction:
ImproveluminanceVSAvoidemission layer composition
Core Design Contradiction:
Illumination intensityVSDevice complexity

Solution Approach 1:

The emission layer employs a composite material system comprising a host compound and a guest compound (heterocyclic compound of Formula 1). This composite approach allows the host to provide structural framework and charge transport while the guest compound contributes to enhanced luminance through its specific photophysical properties, achieving high luminance output without excessive structural complexity

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent optimizes parameters including the molecular structure of the heterocyclic compound (Formula 1), the concentration ratio of guest to host compounds in the emission layer, and the energy level alignment between host and guest materials. These parameter optimizations enable efficient energy transfer and enhanced exciton utilization, improving luminance and energy efficiency simultaneously

Inventive Principle:
Principle #35Parameter changes

2Use of energy by stationary object

If conventional emission layer materials are used, then the manufacturing process is simple, but the energy efficiency and lifespan are limited

Engineering Contradiction:
Improveenergy efficiencyVSAvoidemission layer fabrication
Core Design Contradiction:
Use of energy by stationary objectVSEase of manufacture

Solution Approach 1:

The patent employs parameter optimization by carefully selecting the molecular structures of host and guest compounds, controlling their concentration ratios in the emission layer, and adjusting their energy level alignments. These parameter changes enable efficient energy transfer from host to guest compounds, improving energy efficiency while maintaining compatibility with conventional vacuum deposition manufacturing processes

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The host compound acts as an intermediary material that facilitates energy transfer to the guest compound. The host compound receives charge carriers from electrodes, transports them through the emission layer, and transfers energy to the heterocyclic guest compound, which then emits light. This intermediary mechanism improves energy efficiency without requiring complex direct energy conversion materials

Inventive Principle:
Principle #24Intermediary (Mediator)

3Duration of action of stationary object

If conventional emission layer materials are used, then the device structure is simple, but the lifespan is reduced

Engineering Contradiction:
ImprovelifespanVSAvoidemission layer composition
Core Design Contradiction:
Duration of action of stationary objectVSDevice complexity

Solution Approach 1:

The emission layer uses a composite material system with a host compound and a heterocyclic guest compound (Formula 1). The host compound provides structural stability and charge transport functionality, while the guest compound contributes to enhanced photophysical performance. This composite structure improves device lifespan through better material stability and reduced degradation, without requiring overly complex material compositions

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent employs conventional vacuum deposition techniques and standard emission layer fabrication processes to manufacture the device. By using established manufacturing methods rather than cutting-edge complex processes, the device achieves improved lifespan through better material selection and optimization while maintaining ease of manufacture and cost-effectiveness

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

4Illumination intensity

If conventional materials are used for blue light emission, then the emission layer composition is simple, but the luminance and response speed are insufficient

Engineering Contradiction:
Improveblue light luminanceVSAvoidemission layer composition
Core Design Contradiction:
Illumination intensityVSDevice complexity

Solution Approach 1:

The patent optimizes parameters including the molecular structure of the heterocyclic compound (Formula 1), the concentration ratio of guest to host compounds, and the energy level alignment between materials. These parameter changes enable efficient energy transfer and enhanced exciton utilization in the blue light emission wavelength range, achieving high luminance output without excessive structural complexity

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent replaces conventional single-material emission layers with a two-material composite system (host and guest compounds). This substitution enables more efficient energy transfer mechanisms and improved photophysical performance for blue light emission, achieving higher luminance and faster response speeds through enhanced molecular-level energy interactions rather than relying on simple single-material systems

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The heterocyclic compound improves luminance, energy efficiency, and lifespan of the light-emitting device, particularly in blue light emission, by optimizing the recombination of charge carriers and enhancing exciton generation.

Implementation Method 1

Carriers, such as holes and electrons, recombine in the emission layer to produce excitons. These excitons transition from an excited state to a ground state to thereby generate light.

Methodology Applied
Scientific EffectElectroluminescence: Electroluminescence

Data Source

PatentUS20250261502A1Light-emitting device including heterocyclic compound, electronic apparatus and electronic equipment including the light-emitting device, and the heterocyclic compound
Publication Date: 2025.08.14 SAMSUNG DISPLAY CO LTD
  • US20250261502A1 patent drawing
  • US20250261502A1 patent drawing
  • US20250261502A1 patent drawing

AI summary

Embodiments provide a heterocyclic compound, a light-emitting device including the heterocyclic compound, an electronic apparatus including the light-emitting device, and an electronic equipment including the light-emitting device. The heterocyclic compound is represented by Formula 1, which is explained in the specification: