Heterocyclic Compound Exciplex Formation for OLED Lifespan

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Solution Overview

Problem

Current light-emitting devices face challenges in achieving optimal energy transfer and reducing excessive triplet accumulation, which affects the lifespan and driving voltage of the devices.

Innovation Solution

Incorporation of a heterocyclic compound represented by Formula 1, which facilitates energy transfer by forming an exciplex with an electron-transporting host, improving the device's lifespan and driving voltage characteristics.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional light-emitting devices are used, then basic light emission function is achieved, but excessive triplet accumulation occurs which reduces device lifespan and increases driving voltage

Engineering Contradiction:
Improvedevice lifespanVSAvoidtriplet accumulation
Core Design Contradiction:
ReliabilityVSObject-generated harmful factors

Solution Approach 1:

The patent introduces a heterocyclic compound as an intermediary substance in the emission layer that mediates energy transfer between excitons and the electron-transporting host. This intermediary facilitates efficient energy transfer pathways that prevent triplet accumulation, thereby extending device lifespan and reducing driving voltage requirements

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent modifies the chemical composition parameters of the emission layer by incorporating a specifically designed heterocyclic compound with particular molecular structures (Formula 1). This parameter change in composition enables optimized energy transfer characteristics that reduce triplet accumulation and improve overall device performance

Inventive Principle:
Principle #35Parameter changes

2Power

If conventional emission layers are used, then light emission is achieved, but energy transfer efficiency is suboptimal leading to higher driving voltage

Engineering Contradiction:
Improvedriving voltageVSAvoidenergy transfer efficiency
Core Design Contradiction:
PowerVSUse of energy by moving object

Solution Approach 1:

The heterocyclic compound serves as an energy transfer intermediary that bridges the energy gap between excitons and the electron-transporting host. This mediator enables more efficient energy transfer, reducing energy losses and thereby lowering the driving voltage required for device operation

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent creates a composite emission layer system combining the electron-transporting host with the heterocyclic compound. This composite material system exhibits synergistic energy transfer properties that improve overall energy efficiency and reduce power consumption compared to conventional single-material emission layers

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The heterocyclic compound enhances energy transfer and reduces triplet accumulation, leading to improved lifespan and driving voltage performance in light-emitting devices.

Implementation Method 1

Incorporation of a heterocyclic compound represented by Formula 1, which facilitates energy transfer by forming an exciplex with an electron-transporting host

Methodology Applied
Scientific EffectExciplex formation:

Implementation Method 2

Carriers, such as holes and electrons, recombine in the emission layer to produce excitons. These excitons transition (i.e., relax) from an excited state to a ground state to thereby generate light.

Methodology Applied
Scientific EffectElectroluminescence: Electroluminescence

Data Source

PatentUS20240431201A1Light-emitting device including heterocyclic compound, electronic apparatus including the light-emitting device, and the heterocyclic compound
Publication Date: 2024.12.26 SAMSUNG DISPLAY CO LTD
  • US20240431201A1 patent drawing
  • US20240431201A1 patent drawing
  • US20240431201A1 patent drawing

AI summary

A light-emitting device including a heterocyclic compound and an electronic apparatus including the light-emitting device are provided. The heterocyclic compound described herein is also provided.