Heterocyclic Compound for OLED Efficiency and Lifetime

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Solution Overview

Problem

There is a need for new materials in organic light emitting devices to enhance efficiency, reduce driving voltage, and improve lifetime characteristics.

Innovation Solution

A novel compound represented by Chemical Formula 1 is introduced, which can be used as a material in the organic material layers of the device, serving as a hole injection, hole transport, light emitting, electron transport, or electron injection material, improving the device's efficiency and lifetime.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If conventional organic materials are used in organic light emitting devices, then the device structure is simple, but the efficiency is low and lifetime is short

Engineering Contradiction:
Improvedevice efficiencyVSAvoiddevice lifetime
Core Design Contradiction:
ProductivityVSDuration of action of stationary object

Solution Approach 1:

The patent employs composite organic materials with specific molecular structures containing electron-rich heterocyclic rings (such as triazole, tetrazole, pyrazole) combined with electron-deficient groups. This composite material approach enables simultaneous improvement of charge transport efficiency and device stability, resolving the contradiction between efficiency and lifetime by creating materials that possess multiple beneficial properties in one integrated structure.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent modifies molecular parameters by adjusting the substitution patterns, heteroatom types, and structural configurations of organic compounds. By changing these chemical parameters (such as introducing different heterocyclic rings, adjusting substituent positions), the material achieves optimized charge injection and transport properties while maintaining enhanced stability, thus improving both efficiency and lifetime.

Inventive Principle:
Principle #35Parameter changes

2Productivity

If conventional organic materials are used in organic light emitting devices, then the material selection is simple, but the efficiency and lifetime characteristics are insufficient

Engineering Contradiction:
Improvedevice efficiencyVSAvoiddevice lifetime characteristics
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The patent utilizes composite organic materials featuring electron-rich heterocyclic cores (triazole, tetrazole, pyrazole rings) combined with electron-deficient substituents. This composite structure provides both high charge transport efficiency and improved device reliability by creating materials with balanced electronic properties and enhanced chemical stability.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent introduces functional groups with specific local properties (electron-rich heterocyclic rings at core positions, electron-deficient groups at substituent positions) to create materials with localized charge distribution. This local quality differentiation enables optimized charge injection and transport while enhancing overall material stability and device reliability.

Inventive Principle:
Principle #3Local quality

3Reliability

If new organic materials are developed to improve efficiency and lifetime, then device performance improves, but material complexity increases

Engineering Contradiction:
Improvedevice lifetime characteristicsVSAvoidmaterial structure complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent achieves improved device reliability through systematic parameter changes in molecular structure, specifically by varying heteroatom types (N, O, S), substitution patterns, and ring configurations. While these changes increase material complexity, they are done in a controlled manner using established heterocyclic chemistry, making the complexity manageable and the synthesis routes well-defined.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent introduces specific functional groups with localized electron-rich or electron-deficient characteristics at defined positions in the molecular structure. This localized approach to complexity allows for targeted optimization of charge transport and stability properties without requiring complete redesign of the entire molecular structure, thus managing complexity effectively.

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The compound enhances the efficiency and reduces the driving voltage of organic light emitting devices while improving their lifetime characteristics, making it suitable for various organic material layers.

Implementation Method 1

the holes are injected from an anode into the organic material layer

Methodology Applied
Scientific EffectCharge injection:

Implementation Method 2

hole transport material

Methodology Applied
Scientific EffectCharge transport:

Implementation Method 3

the electrons are injected from the cathode into the organic material layer

Methodology Applied
Scientific EffectCharge injection:

Implementation Method 4

electron transport material

Methodology Applied
Scientific EffectCharge transport:

Implementation Method 5

when the injected holes and electrons meet each other, an exciton is formed, and light is emitted when the exciton falls to a ground state again

Methodology Applied
Scientific EffectElectroluminescence: Electroluminescence

Data Source

PatentUS12058931B2Heterocyclic compound and organic light emitting device comprising same
Publication Date: 2024.08.06 LG CHEM LTD
  • US12058931B2 patent drawing
  • US12058931B2 patent drawing
  • US12058931B2 patent drawing

AI summary

A heterocyclic compound represented by Chemical Formula 1 and an organic light emitting device comprising the same, and the heterocyclic compound providing improved efficiency, low driving voltage, and improved lifetime characteristics of the organic light emitting device.