Heterocyclic Compound for OLED Efficiency and Stability

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Solution Overview

Problem

Current organic light-emitting devices (OLEDs) face challenges in achieving high efficiency, low driving voltage, and long lifespan due to limitations in charge transport and light-emitting materials, particularly with tris(2-phenylpyridine)iridium(Ir(ppy)3, which has low efficiency and stability issues.

Innovation Solution

A heterocyclic compound represented by Formula 1 is used in the organic layer of OLEDs, providing high charge transporting capability, light-emitting efficiency, and stability, with applications as an electron transport material or light-emitting material, enhancing the device's performance by forming a structure with a substrate, anode, hole transport layer, emission layer, and cathode.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If conventional materials like Ir(ppy)3 are used in OLEDs, then the device can achieve light emission, but the efficiency and stability are limited

Engineering Contradiction:
Improvelight-emitting efficiencyVSAvoiddevice stability
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The patent employs composite material strategies by combining the heterocyclic compound (Formula 1) with complementary organic materials in the OLED structure. The compound serves dual functions as both host material and electron transport material, creating a composite system that achieves high efficiency and stability simultaneously. This is evident in the embodiment where the heterocyclic compound replaces conventional single-material approaches with a multifunctional composite material system.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent utilizes parameter changes by modifying the molecular structure of the organic compound according to Formula 1, where R1-R8 represent various substituent groups that can be adjusted to optimize performance. By changing structural parameters such as substituent types and positions, the patent achieves optimal balance between electron transport capability, charge transport efficiency, and operational stability without sacrificing light-emitting performance.

Inventive Principle:
Principle #35Parameter changes

2Ease of manufacture

If the OLED structure is simplified, then manufacturing becomes easier, but charge transport capability may be compromised

Engineering Contradiction:
Improvedevice fabricationVSAvoidcharge transport capability
Core Design Contradiction:
Ease of manufactureVSReliability

Solution Approach 1:

The heterocyclic compound of Formula 1 exhibits multi-functionality by serving as both the host material and electron transport material in the OLED emission layer. This universal material approach simplifies the device structure and manufacturing process while maintaining excellent charge transport capability, as the single compound performs multiple critical functions that would otherwise require separate materials and layers.

Inventive Principle:
Principle #6Universality (Multi-functionality)

Solution Approach 2:

The patent merges the host material function and electron transport material function into a single heterocyclic compound system. This combining of functions reduces the number of separate materials and processing steps required, easing manufacturing while ensuring adequate charge transport capability through the compound's inherent electron mobility properties.

Inventive Principle:
Principle #5Merging (Combining)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The heterocyclic compound improves OLED efficiency, reduces driving voltage, and significantly prolongs the device's lifespan, offering high durability and stability against thermal stress and environmental factors.

Implementation Method 1

providing high charge transporting capability

Methodology Applied
Scientific EffectElectron transport: Conduction (electrical)

Implementation Method 2

organic light-emitting device

Methodology Applied
Scientific EffectElectroluminescence: Electroluminescence

Data Source

PatentUS9537108B2Heterocyclic compound and organic light-emitting device including the same
Publication Date: 2017.01.03 SAMSUNG DISPLAY CO LTD
  • US9537108B2 patent drawing
  • US9537108B2 patent drawing
  • US9537108B2 patent drawing

AI summary

Provided is a heterocyclic compound represented by Formula 1 below and an organic light-emitting device including the same.In Formula 1, R1 to R8 are each independently a hydrogen atom, a deuterium atom, a substituted or unsubstituted C1 to C60 alkyl group, a substituted or unsubstituted C3 to C60 cycloalkyl group, a substituted or unsubstituted C2 to C60 heteroaryl group, a substituted or unsubstituted C6 to C60 aryl group, or a substituted or unsubstituted C6 to C60 condensed polycyclic group, with the proviso that R2 is notwherein X is O, S, or Se.