Heterocyclic Compound for OLED Hole Transport and Electron Blocking

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Solution Overview

Problem

Current organic light-emitting devices face challenges in achieving low driving voltage, high luminous efficiency, and extended lifetime, which are crucial for improving their performance and efficiency.

Innovation Solution

A heterocyclic compound represented by Formula 1 is introduced, which can be used as a material for the organic layer in OLEDs, specifically for hole transport and electron-blocking layers, to enhance the device's performance by optimizing the energy band gap and improving interfacial properties.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Use of energy by moving object

If conventional organic materials are used in OLEDs, then the device structure is simple, but the driving voltage is high and luminous efficiency is low

Engineering Contradiction:
Improveluminous efficiencyVSAvoiddriving voltage
Core Design Contradiction:
Use of energy by moving objectVSPower

Solution Approach 1:

The patent modifies the molecular structure of organic compounds by introducing specific heterocyclic groups (oxadiazole, triazole, pyrimidine, etc.) and substituent patterns to optimize energy levels, HOMO-LUMO gaps, and charge transport properties. This structural parameter optimization enables simultaneous achievement of low driving voltage and high luminous efficiency

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent designs composite organic materials combining multiple functional moieties (electron-transporting groups, hole-transporting groups, and blocking groups) within single molecular structures. These composite molecules exhibit synergistic effects that improve both voltage characteristics and luminous efficiency beyond what single-function materials can achieve

Inventive Principle:
Principle #40Composite materials

2Duration of action of stationary object

If conventional organic materials are used in OLEDs, then material synthesis is straightforward, but device lifetime is short

Engineering Contradiction:
Improvedevice lifetimeVSAvoidmaterial synthesis complexity
Core Design Contradiction:
Duration of action of stationary objectVSEase of manufacture

Solution Approach 1:

The patent introduces specific molecular parameters including rigid heterocyclic cores, strategic substituent positioning, and molecular weight optimization to enhance thermal stability, morphological stability, and resistance to electrochemical degradation. These parameter optimizations extend device lifetime while maintaining synthetic feasibility through modular molecular design

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs commercially available building blocks and standard organic synthesis techniques to create stable organic materials, avoiding the need for rare or difficult-to-synthesize compounds. This approach extends device lifetime through material stability rather than through complex or expensive synthesis procedures

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

3Reliability

If multi-layer organic structure is used, then functional performance is improved, but device complexity increases

Engineering Contradiction:
Improvefunctional performanceVSAvoidlayer structure complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent designs organic compounds that can perform multiple functions simultaneously or in different device configurations. The heterocyclic compounds can serve as hole transport materials, electron transport materials, or blocking layer materials depending on their specific molecular structure and energy level alignment, reducing the need for separate specialized layers

Inventive Principle:
Principle #6Universality (Multi-functionality)

Solution Approach 2:

The patent creates materials with tunable properties that can adapt to different device architectures and functional requirements. By adjusting substituent groups and molecular configuration, the same base compound can be optimized for different layers or device types, providing flexibility without increasing structural complexity

Inventive Principle:
Principle #15Dynamics

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The heterocyclic compound significantly reduces driving voltage, improves luminous efficiency, and extends the lifetime of organic light-emitting devices by effectively functioning as a hole transport and electron-blocking layer, offering superior thermal stability and performance.

Implementation Method 1

the heterocyclic compound represented by Formula 1... effectively functioning as a hole transport and electron-blocking layer

Methodology Applied
Scientific EffectCharge transport: Conduction (electrical)

Data Source

PatentUS20240130227A1Heterocyclic compound, organic electroluminescent device comprising same, and composition for organic layer
Publication Date: 2024.04.18 LT MATERIALS CO LTD
  • US20240130227A1 patent drawing
  • US20240130227A1 patent drawing
  • US20240130227A1 patent drawing

AI summary

The present invention provides a heterocyclic compound represented by Formula 1 and an organic light-emitting device comprising the same.