Heterocyclic Compound for OLED Electron Injection

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

Current organic light emitting devices face challenges in achieving efficient electron transfer and injection, leading to high driving voltage and reduced lifetime, necessitating the development of materials with enhanced electron control abilities.

Innovation Solution

A heterocyclic compound with a specific chemical structure, represented by Chemical Formula 1, is introduced, which can be used in the electron injection, transfer, and control layers to improve electron mobility and reduce driving voltage, featuring a nonlinear structure with a substituent that enhances dipole moment and amorphous layer formation.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Use of energy by moving object

If conventional organic materials are used in electron injection and transfer layers, then the device structure is simple, but the driving voltage is high and electron mobility is poor

Engineering Contradiction:
Improvedriving voltageVSAvoidmaterial structure complexity
Core Design Contradiction:
Use of energy by moving objectVSDevice complexity

Solution Approach 1:

The patent modifies the molecular structure parameters of organic materials by introducing specific heterocyclic groups (triazine, pyrimidine, pyridine rings) and substituent patterns to optimize electron affinity and LUMO energy levels, thereby improving electron injection and transfer efficiency while reducing driving voltage

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs composite molecular structures combining multiple heterocyclic units (e.g., spirobifluorene core with triazine/pyrimidine substituents) to achieve synergistic effects that enhance both electron mobility and device stability without requiring complex multi-layer architectures

Inventive Principle:
Principle #40Composite materials

2Duration of action of stationary object

If conventional materials are used, then the manufacturing process is simple, but the device lifetime is reduced

Engineering Contradiction:
Improvedevice lifetimeVSAvoidmaterial synthesis complexity
Core Design Contradiction:
Duration of action of stationary objectVSEase of manufacture

Solution Approach 1:

The patent optimizes molecular weight, glass transition temperature, and thermal stability parameters of the organic materials through careful selection of heterocyclic units and substituents, ensuring long-term device operation stability while maintaining compatibility with standard vacuum deposition processes

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent uses readily available heterocyclic building blocks and standard organic synthesis routes to create stable electron transfer materials, avoiding the need for expensive or complex multi-step manufacturing processes while achieving enhanced device lifetime

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

3Productivity

If standard organic materials are used, then the device structure is straightforward, but light emission efficiency is low

Engineering Contradiction:
Improvelight emission efficiencyVSAvoidmolecular structure complexity
Core Design Contradiction:
ProductivityVSDevice complexity

Solution Approach 1:

The patent introduces electron-deficient heterocyclic groups (triazine, pyrimidine, pyridine) at specific positions on the molecular core to create localized electron transfer pathways, enhancing electron mobility and recombination efficiency without requiring complex overall molecular architectures

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The patent combines electron-rich spirobifluorene cores with electron-deficient heterocyclic substituents to create push-pull molecular systems that facilitate efficient charge separation and recombination, thereby improving light emission efficiency through intramolecular charge transfer mechanisms

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The heterocyclic compound effectively lowers driving voltage, increases light emission efficiency, and enhances the lifetime of organic light emitting devices by strengthening electron mobility and stability.

Implementation Method 1

having excellent electron transfer, electron injection and electron control abilities, and, when used in an organic material layer of an organic light emitting device, particularly, an electron injection layer, an electron transfer layer

Methodology Applied
Scientific EffectElectron mobility enhancement: Conduction (electrical)

Implementation Method 2

An organic light emission phenomenon generally refers to a phenomenon converting electrical energy to light energy using an organic material

Methodology Applied
Scientific EffectElectroluminescence: Electroluminescence

Data Source

PatentUS11450819B2Heterocyclic compound and organic light-emitting element including same
Publication Date: 2022.09.20 LG CHEM LTD
  • US11450819B2 patent drawing
  • US11450819B2 patent drawing
  • US11450819B2 patent drawing

AI summary

The present specification relates to a heterocyclic compound represented by Chemical Formula 1 and an organic light emitting device comprising the same.