Heterocyclic Compound for OLED Electron Transfer and Stability

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Solution Overview

Problem

Current organic light emitting devices face challenges in enhancing performance, lifetime, and efficiency due to limitations in materials used for the organic thin film, particularly in terms of electron transfer and hole blocking layers.

Innovation Solution

A heterocyclic compound represented by Chemical Formula 1 is introduced, which can be used as a material for the organic light emitting device, specifically in the electron transfer layer, hole blocking layer, or charge generation layer, offering improved electron delocalization and stability, thereby reducing driving voltage and enhancing light efficiency and device lifetime.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional organic thin film materials are used, then device structure is simple, but performance, lifetime and efficiency are limited

Engineering Contradiction:
Improvedevice lifetimeVSAvoidmaterial structure complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent modifies the molecular structure of organic compounds by changing parameters such as introducing heterocyclic rings (pyridine, pyrimidine, triazine), adjusting substituent groups (R1-R6), and varying molecular weight and conjugation length. These parameter changes enhance electron delocalization, improve charge transfer efficiency, and extend device lifetime while maintaining reasonable structural complexity

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs composite material strategies by combining heterocyclic aromatic rings with various substituent groups (alkyl, aryl, heterocyclic groups) to create compounds with tailored properties. The composite structure of core heterocyclic units with functional substituents enables simultaneous optimization of electron transfer, hole blocking, and device stability

Inventive Principle:
Principle #40Composite materials

2Productivity

If conventional materials are used, then manufacturing is simple, but electron transfer efficiency and light emission efficiency are insufficient

Engineering Contradiction:
Improvelight emission efficiencyVSAvoidcompound structure complexity
Core Design Contradiction:
ProductivityVSDevice complexity

Solution Approach 1:

The patent optimizes light emission efficiency by changing molecular parameters including extending conjugation systems through fused heterocyclic rings, adjusting HOMO-LUMO energy gaps via substituent selection, and modifying molecular planarity. These changes enhance electron delocalization and radiative recombination efficiency

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent segments the organic compound into distinct functional modules: core heterocyclic units (pyridine, pyrimidine, triazine rings) for electron transfer, linking groups (L1-L3) for structural connectivity, and substituent groups (R1-R6) for property tuning. This modular segmentation enables systematic optimization of light emission efficiency

Inventive Principle:
Principle #1Segmentation

3Power

If existing organic thin film materials are used, then device operation is simple, but driving voltage remains high

Engineering Contradiction:
Improvedriving voltageVSAvoidmaterial composition complexity
Core Design Contradiction:
PowerVSDevice complexity

Solution Approach 1:

The patent reduces driving voltage by changing electronic parameters of the organic materials, specifically adjusting electron affinity, ionization potential, and charge mobility through heterocyclic structure design. The modified compounds facilitate easier charge injection and transport, lowering the voltage required for device operation

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The use of the heterocyclic compound results in lower driving voltage, increased light emission efficiency, and extended device lifetime by facilitating efficient electron transfer and stabilizing the device structure.

Implementation Method 1

offering improved electron delocalization and stability, thereby reducing driving voltage

Methodology Applied
Scientific EffectElectron delocalization:

Implementation Method 2

electrons and holes injected from the two electrodes bind and pair in the organic thin film, and light emits as these annihilate

Methodology Applied
Scientific EffectElectroluminescence: Electroluminescence

Data Source

PatentUS20220223795A1Heterocyclic compound and organic light emitting device comprising same
Publication Date: 2022.07.14 LT MATERIALS CO LTD
  • US20220223795A1 patent drawing
  • US20220223795A1 patent drawing
  • US20220223795A1 patent drawing

AI summary

The present specification relates to a heterocyclic compound represented by Chemical Formula 1, and an organic light emitting device including the same.