Heterocyclic Compound for OLED Electron Transfer and Lifetime

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Solution Overview

Problem

Current organic light emitting devices face challenges in enhancing performance, lifetime, and efficiency due to limitations in materials used for the organic thin film, particularly in terms of hole injection, hole transfer, electron blocking, and electron injection functions.

Innovation Solution

A heterocyclic compound represented by Chemical Formula 1 is introduced, which can serve as a material for organic light emitting devices, acting as a hole injection material, hole transfer material, light emitting material, electron transfer material, and electron injection material, specifically functioning as an electron transfer layer material, hole blocking layer material, or charge generation layer material, thereby improving device performance.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional organic thin film materials are used, then the device structure is simple, but the performance, lifetime and efficiency are insufficient

Engineering Contradiction:
Improvedevice lifetimeVSAvoidmaterial layer structure
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The heterocyclic compound is designed to perform multiple functions simultaneously: electron transfer, hole blocking, and charge generation. This multi-functionality allows a single material layer to replace what would traditionally require multiple separate layers, thereby improving device lifetime and efficiency without proportionally increasing structural complexity

Inventive Principle:
Principle #6Universality (Multi-functionality)

Solution Approach 2:

The patent employs composite material strategies by combining the heterocyclic compound with other organic materials in specific layer configurations. The compound's core structure with可调 substituents allows it to function as part of a composite system that optimizes both performance and stability, resolving the contradiction between reliability improvement and complexity management

Inventive Principle:
Principle #40Composite materials

2Productivity

If conventional materials are used for organic thin film, then manufacturing is simple, but hole injection, hole transfer, electron blocking and electron injection functions are insufficient

Engineering Contradiction:
Improvecharge transfer efficiencyVSAvoidmaterial deposition process
Core Design Contradiction:
ProductivityVSEase of manufacture

Solution Approach 1:

The heterocyclic compound features a tunable molecular structure with variable substituents (R1-R6, X, Y, Z) that allow precise adjustment of electronic properties such as HOMO/LUMO energy levels, electron mobility, and hole blocking capability. By changing molecular parameters rather than process parameters, the patent achieves high charge transfer efficiency while maintaining manufacturing simplicity

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The organic thin film is segmented into functionally distinct layers (electron transfer layer, hole blocking layer, charge generation layer), with the heterocyclic compound specifically assigned to certain layers based on its electronic properties. This segmentation allows each layer to be optimized independently for its specific function, improving overall charge transfer efficiency without complicating the manufacturing of individual layers

Inventive Principle:
Principle #1Segmentation

3Power

If existing organic material layers are used, then device structure is straightforward, but light efficiency and driving voltage are not optimized

Engineering Contradiction:
Improvelight efficiencyVSAvoidorganic material layer configuration
Core Design Contradiction:
PowerVSDevice complexity

Solution Approach 1:

The patent applies local quality optimization by placing the heterocyclic compound with specific electronic properties in particular locations within the device structure (electron transfer layer, hole blocking layer, or charge generation layer). The compound's local electronic characteristics (electron affinity, hole blocking ability) are matched to the specific functional requirements of each layer, maximizing light efficiency without requiring complex overall device architecture

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The heterocyclic compound's ability to perform multiple functions (electron transfer, hole blocking, charge generation) allows it to be strategically positioned in different layers depending on device optimization needs. This multi-functionality enables a single material to address multiple performance parameters (light efficiency, driving voltage) simultaneously, reducing the need for complex multi-material layer configurations

Inventive Principle:
Principle #6Universality (Multi-functionality)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The use of the heterocyclic compound reduces driving voltage, enhances light efficiency, and extends the lifetime of organic light emitting devices by facilitating better electron transfer and stability in the excited state, leading to improved balance and efficiency in the light emitting layer.

Implementation Method 1

the compound is capable of performing a role of a hole injection material, a hole transfer material, a light emitting material, an electron transfer material, an electron injection material

Methodology Applied
Scientific EffectElectron transfer: Conduction (electrical)

Implementation Method 2

When a voltage is applied to an organic light emitting device having such a structure, electrons and holes injected from the two electrodes bind and pair in the organic thin film, and light emits as these annihilate

Methodology Applied
Scientific EffectElectroluminescence: Electroluminescence

Data Source

PatentUS12089493B2Heterocyclic compound and organic light emitting device comprising same
Publication Date: 2024.09.10 LT MATERIALS CO LTD
  • US12089493B2 patent drawing
  • US12089493B2 patent drawing
  • US12089493B2 patent drawing

AI summary

The present specification relates to a heterocyclic compound represented by Chemical Formula 1, and an organic light emitting device comprising the same.