Heterocyclic Compound Composition for OLED Electron Transport

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Solution Overview

Problem

Existing organic light-emitting devices face challenges in achieving high luminance efficiency and long lifespan, particularly in terms of electron transport characteristics and energy level differences.

Innovation Solution

Incorporation of a heterocyclic compound represented by Formula 1, which is π-electron-deficient and enhances electron transport characteristics, leading to improved luminance efficiency and a larger energy gap, thereby facilitating low driving voltage and extended device lifespan.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If conventional organic light-emitting devices are used, then device structure is simple, but luminance efficiency is low and lifespan is short

Engineering Contradiction:
Improveluminance efficiencyVSAvoiddevice lifespan
Core Design Contradiction:
ProductivityVSDuration of action of stationary object

Solution Approach 1:

The patent changes the chemical composition parameters by introducing a heterocyclic compound with specific structural features (Formula 1) containing electron-deficient nitrogen-containing cyclic groups. This parameter change in molecular structure leads to improved electron transport characteristics, higher luminance efficiency, and extended device lifespan without fundamentally altering the device architecture.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs a composite material approach by combining the heterocyclic compound (Formula 1) with other organic materials in the emission layer and electron transport region. This composite material system synergistically improves electron transport, reduces energy loss, and enhances both luminance efficiency and device stability over time.

Inventive Principle:
Principle #40Composite materials

2Productivity

If electron transport characteristics are improved, then luminance efficiency increases, but energy level differences increase

Engineering Contradiction:
Improveluminance efficiencyVSAvoidenergy level difference
Core Design Contradiction:
ProductivityVSUse of energy by moving object

Solution Approach 1:

The patent applies local quality by designing the heterocyclic compound with specific functional groups at different positions: the electron-deficient nitrogen-containing cyclic group (EW1) at one location enhances electron acceptance and transport, while the electron-rich cyclic groups (Ar1 and Ar2) at other locations provide electron donation. This spatial distribution of electron-deficient and electron-rich regions optimizes energy levels and improves luminance efficiency while managing energy gaps.

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The heterocyclic compound improves electron transport and increases the energy gap, resulting in a light-emitting device with enhanced luminance efficiency and a longer lifespan.

Implementation Method 1

Incorporation of a heterocyclic compound represented by Formula 1, which is π-electron-deficient and enhances electron transport characteristics

Methodology Applied
Scientific EffectElectron transport: Conduction (electrical)

Implementation Method 2

leading to improved luminance efficiency and a larger energy gap, thereby facilitating low driving voltage

Methodology Applied
Scientific EffectEnergy gap:

Implementation Method 3

Carriers, such as the holes and the electrons, recombine in the emission layer to produce excitons. These excitons transit from an excited state to a ground state to thereby generate light.

Methodology Applied
Scientific EffectElectroluminescence: Electroluminescence

Data Source

PatentUS12402525B2Heterocyclic compound, light-emitting device including the same, and electronic apparatus including the light-emitting device
Publication Date: 2025.08.26 SAMSUNG DISPLAY CO LTD
  • US12402525B2 patent drawing
  • US12402525B2 patent drawing
  • US12402525B2 patent drawing

AI summary

Provided is a heterocyclic compound represented by Formula 1, a light-emitting device including the same, and an electronic apparatus including the light-emitting device. The light-emitting device includes a first electrode, a second electrode facing the first electrode, an interlayer between the first electrode and the second electrode and including an emission layer, and the heterocyclic compound represented by Formula 1.