Novel Heterocyclic Compound for OLED Electron Transport

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Solution Overview

Problem

Current organic electronic devices, particularly top emission OLEDs, face challenges in improving operating voltage and efficiency due to suboptimal electronic properties of compounds used in electron transport layers.

Innovation Solution

A novel compound with the formula (I) is introduced, featuring specific aromatic rings and spacer units that enhance the performance of organic electronic devices by improving the balance of hole and electron injection, leading to better voltage and efficiency characteristics.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Power

If conventional compounds are used in electron transport layers, then device structure is simple, but operating voltage and efficiency are insufficient

Engineering Contradiction:
Improveoperating voltage and efficiencyVSAvoidcompound structure complexity
Core Design Contradiction:
PowerVSDevice complexity

Solution Approach 1:

The patent modifies the molecular structure parameters of electron transport compounds by introducing specific heterocyclic rings (triazine, pyrimidine, pyridine) and adjusting substituent positions (R1-R6 groups) to optimize electronic properties, achieving improved operating voltage and efficiency without excessive structural complexity

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates composite molecular structures combining multiple heterocyclic rings (e.g., benzo[4,5]imidazo[1,2-a]quinolinylene core with triazine or pyrimidine rings) to achieve synergistic effects that improve charge transport properties and device performance

Inventive Principle:
Principle #40Composite materials

2Reliability

If electron transport layer compounds have simple structure, then ease of manufacture is high, but charge injection balance is poor

Engineering Contradiction:
Improvecharge injection balanceVSAvoidsynthesis complexity
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The patent introduces specific functional groups and substituent patterns at localized positions (R1-R6) on the molecular core to enhance charge injection balance without requiring complete restructuring of the entire molecule, maintaining reasonable synthesis complexity

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The patent uses heterocyclic rings (triazine, pyrimidine, pyridine) as intermediary structures that mediate between the electron transport function and the molecular stability, improving charge injection balance while maintaining manufacturability through well-established synthesis routes

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The use of the novel compound in electron transport layers results in improved operating voltage and efficiency of organic electronic devices, specifically top emission OLEDs, by optimizing the balance of charge injection and transport.

Implementation Method 1

electrons injected from the cathode electrode move to the EML, via the ETL

Methodology Applied
Scientific EffectElectron transport: Conduction (electrical)

Implementation Method 2

holes injected from the anode electrode move to the EML, via the HTL

Methodology Applied
Scientific EffectHole transport: Conduction (electrical)

Implementation Method 3

The holes and electrons recombine in the EML to generate excitons. When the excitons drop from an excited state to a ground state, light is emitted

Methodology Applied
Scientific EffectElectroluminescence: Electroluminescence

Data Source

PatentUS12144253B2Compound and an organic semiconducting layer, an organic electronic device and a display or lighting device comprising the same
Publication Date: 2024.11.12 NOVALED GMBH
  • US12144253B2 patent drawing
  • US12144253B2 patent drawing
  • US12144253B2 patent drawing

AI summary

The present invention relates to a compound having the formula (I); and an organic semiconducting layer, an organic electronic device, a display device and a lighting device comprising the same.