Heterocyclic Compound for OLED Emission and Electron Transport

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Solution Overview

Problem

Existing organic light-emitting diodes face challenges in achieving low voltage, high brightness, and long lifetime due to limitations in the materials used for the emission and electron transport layers.

Innovation Solution

A heterocyclic compound represented by Formula 1 is introduced, which serves as both an emission material and electron transport material, enhancing light emission efficiency and thermal stability, and is incorporated into the organic light-emitting diode structure.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional organic compounds are used for emission and electron transport layers, then the device structure is simple, but the driving voltage is high and lifetime is short

Engineering Contradiction:
Improvedevice lifetimeVSAvoidmaterial structure complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The heterocyclic compound serves dual functions as both emission material and electron transport material in the organic light-emitting diode. This multi-functionality reduces the number of separate materials needed while achieving both high brightness and long lifetime through the compound's unique molecular structure containing heterocyclic rings with electron-deficient characteristics.

Inventive Principle:
Principle #6Universality (Multi-functionality)

2Illumination intensity

If conventional organic compounds are used, then the manufacturing process is simple, but brightness and efficiency are insufficient

Engineering Contradiction:
ImprovebrightnessVSAvoidmaterial synthesis complexity
Core Design Contradiction:
Illumination intensityVSEase of manufacture

Solution Approach 1:

The invention modifies the molecular parameters of organic compounds by introducing heterocyclic ring structures with specific electron-deficient characteristics. This changes the electronic and optical parameters of the material, resulting in enhanced brightness and efficiency while maintaining feasibility in manufacturing through established organic synthesis methods.

Inventive Principle:
Principle #35Parameter changes

3Stability of the object's composition

If conventional materials are used for emission and electron transport layers, then the device structure is simple, but thermal stability is poor

Engineering Contradiction:
Improvethermal stabilityVSAvoidcompound structure complexity
Core Design Contradiction:
Stability of the object's compositionVSDevice complexity

Solution Approach 1:

The invention creates a composite molecular structure by combining heterocyclic rings with electron-deficient characteristics into the organic compound framework. This composite structure provides enhanced thermal stability and molecular rigidity, allowing the single compound to function effectively as both emission and electron transport material under thermal stress conditions.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The heterocyclic compound improves the organic light-emitting diode's performance by reducing driving voltage, increasing brightness, and extending the device's lifetime, making it suitable for high-quality flat display devices.

Implementation Method 1

electrons injected from the cathode pass the electron transport layer to the emission layer

Methodology Applied
Scientific EffectElectron transport: Conduction (electrical)

Implementation Method 2

The holes and electrons, which are carriers, are recombined in the emission layer to generate excitons, which then change from an excited state to a ground state, thereby generating light

Methodology Applied
Scientific EffectElectroluminescence: Electroluminescence

Data Source

PatentUS9312497B2Heterocyclic compound, organic light-emitting diode including the heterocyclic compound, and flat display device including the organic light-emitting diode
Publication Date: 2016.04.12 SAMSUNG DISPLAY CO LTD
  • US9312497B2 patent drawing
  • US9312497B2 patent drawing
  • US9312497B2 patent drawing

AI summary

Provided are a heterocyclic compound represented by Formula 1 below, and an organic light-emitting diode and a flat display device each including the heterocyclic compound.The organic light-emitting diode including an organic layer including the heterocyclic compound has a low driving voltage, high luminescence efficiency, and long lifetime.