Heterocyclic Compound for OLED Hole Transport and Stability

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Solution Overview

Problem

Current organic light emitting devices face challenges in improving performance, service life, and efficiency due to limitations in materials for organic thin films, particularly in hole transport and light emission layers.

Innovation Solution

A heterocyclic compound with a benzofurocarbazole or benzothienocarbazole core is developed, which forms resonance structures, enhancing hole characteristics and reducing hole traps, and is used in various layers of the organic light emitting device, including hole injection, transport, emission, and injection layers, along with another compound to improve driving voltage and service life.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional organic thin film materials are used, then the device structure is simple, but the performance, service life, and efficiency are limited

Engineering Contradiction:
Improveservice lifeVSAvoidmaterial structure complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent modifies the molecular structure parameters of organic compounds by introducing specific heterocyclic cores (carbazole, dibenzofuran, dibenzothiophene) with varying substituent patterns. This changes the electronic and steric parameters of the materials to achieve improved hole transport properties and enhanced device reliability without excessive structural complexity

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs composite material design by combining different heterocyclic core structures with various substituent groups (e.g., carbazole cores with dibenzofuran or dibenzothiophene substituents). This creates multi-functional organic compounds that simultaneously provide hole injection, transport, and emission functions, improving service life while maintaining manageable material complexity

Inventive Principle:
Principle #40Composite materials

2Productivity

If conventional organic thin film materials are used, then the manufacturing process is simple, but the efficiency and driving stability are insufficient

Engineering Contradiction:
ImproveefficiencyVSAvoidmaterial synthesis complexity
Core Design Contradiction:
ProductivityVSEase of manufacture

Solution Approach 1:

The patent segments the organic compound structure into distinct functional modules: heterocyclic cores providing hole transport and emission, and substituent groups providing energy level tuning and stability. This modular approach enables independent optimization of each function while simplifying the overall synthesis process through standardized coupling reactions

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The patent systematically varies molecular parameters such as substituent types, positions, and configurations to optimize efficiency. By changing these parameters in a controlled manner, the patent achieves enhanced device efficiency while maintaining synthesis feasibility through established organic chemistry methodologies

Inventive Principle:
Principle #35Parameter changes

3Power

If conventional materials are used, then the device structure is simple, but the hole transport performance and light emission efficiency are limited

Engineering Contradiction:
Improvelight emission efficiencyVSAvoidmolecular structure complexity
Core Design Contradiction:
PowerVSDevice complexity

Solution Approach 1:

The patent applies local quality modification by introducing specific heterocyclic moieties at particular positions within the molecular structure. The carbazole, dibenzofuran, or dibenzothiophene groups are strategically placed to provide localized hole transport enhancement and emission properties, improving light emission efficiency without requiring complex overall molecular architecture

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The heterocyclic compounds improve hole transfer and thermal stability, leading to enhanced driving stability and service life of the organic light emitting device by lowering driving voltage and increasing light efficiency.

Implementation Method 1

the heterocyclic compound forms resonance structures, enhancing hole characteristics

Methodology Applied
Scientific EffectResonance: Resonance

Implementation Method 2

electrons and holes injected from the two electrodes combine with each other in an organic thin film to make a pair, and then, emit light while being extinguished

Methodology Applied
Scientific EffectElectroluminescence: Electroluminescence

Data Source

PatentUS20240174687A1Heterocyclic compound, organic light emitting device comprising same and composition for organic layer of organic light emitting device
Publication Date: 2024.05.30 LT MATERIALS CO LTD
  • US20240174687A1 patent drawing
  • US20240174687A1 patent drawing
  • US20240174687A1 patent drawing

AI summary

Disclosed are a heterocyclic compound represented by Chemical Formula 1, and an organic light emitting device and a composition for an organic material layer, including the same.