Heterocyclic Compound for OLED Efficiency and Stability

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Solution Overview

Problem

The development of new organic materials for organic light emitting devices is required to enhance their efficiency and stability, as existing materials face challenges in achieving optimal energy levels, electrochemical stability, and thermal stability.

Innovation Solution

A heterocyclic compound represented by Chemical Formula 1 is introduced, which is used in the organic light emitting device, providing a proper energy level and excellent electrochemical and thermal stability, and is incorporated into various organic material layers such as the electron transfer layer, electron injection layer, or light emitting layer.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If conventional organic materials are used in organic light emitting devices, then the device structure is simpler, but the efficiency and stability are insufficient

Engineering Contradiction:
Improvedevice efficiencyVSAvoidmaterial structure complexity
Core Design Contradiction:
ProductivityVSDevice complexity

Solution Approach 1:

The patent modifies the molecular structure parameters of organic materials by introducing specific heterocyclic groups (triazine, pyrimidine, pyridine rings) and substituent patterns to optimize HOMO levels and electrochemical stability, thereby improving device efficiency and stability without requiring complex device architecture

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent develops composite organic materials combining multiple heterocyclic units (e.g., triazine-pyrimidine hybrids, carbazole-benzimidazole combinations) to achieve synergistic effects that simultaneously improve efficiency, electrochemical stability, and thermal stability while maintaining reasonable structural complexity

Inventive Principle:
Principle #40Composite materials

2Productivity

If materials with high light emission efficiency are used, then the light emission performance is improved, but the electrochemical stability deteriorates

Engineering Contradiction:
Improvelight emission efficiencyVSAvoidelectrochemical stability
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The patent applies local quality by introducing electron-withdrawing heterocyclic groups (triazine, pyrimidine rings) at specific positions of the molecular structure to create localized regions of different electron density, which simultaneously enhances light emission efficiency through improved exciton formation while maintaining electrochemical stability through distributed charge distribution

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The patent uses heterocyclic aromatic rings as intermediary structures that mediate between electron-donating and electron-withdrawing groups, facilitating efficient charge transfer and exciton formation for high light emission efficiency while the aromatic stability of the heterocyclic core provides electrochemical stability

Inventive Principle:
Principle #24Intermediary (Mediator)

3Reliability

If materials with deep HOMO level are used, then the driving stability is improved, but the manufacturing complexity increases

Engineering Contradiction:
Improvedriving stabilityVSAvoidsynthesis complexity
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The patent segments the molecular structure into modular heterocyclic units (triazine rings, pyrimidine rings, pyridine rings) that can be independently synthesized and then coupled through standardized condensation reactions, thereby achieving deep HOMO levels through systematic molecular design while maintaining relatively simple and scalable synthesis procedures

Inventive Principle:
Principle #1Segmentation

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The heterocyclic compound improves the efficiency and driving stability of the organic light emitting device by providing a deep HOMO level and thermal stability, leading to superior performance in terms of efficiency and stability when used in the device's organic material layers.

Implementation Method 1

An organic light emission phenomenon is one of the examples converting current to visible light by an internal process of a specific organic molecule

Methodology Applied
Scientific EffectElectroluminescence: Electroluminescence

Implementation Method 2

electrons and holes flow into the organic material layer from the cathode and the anode, respectively. The electrons and the holes injected to the organic material layer are recombined to form excitons

Methodology Applied
Scientific EffectCharge injection and transfer: Conduction (electrical)

Data Source

PatentUS10734590B2Heterocyclic compound and organic light-emitting element using same
Publication Date: 2020.08.04 LG CHEM LTD
  • US10734590B2 patent drawing
  • US10734590B2 patent drawing
  • US10734590B2 patent drawing

AI summary

The present specification provides a heterocyclic compound and an organic light emitting device using the same.