Heterocyclic Compound for OLED Internal Quantum Efficiency

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Solution Overview

Problem

Current organic light-emitting devices face limitations in achieving high internal quantum efficiency, luminance, and long lifespan due to suboptimal charge transport capabilities and exciton formation ratios in the emission layer.

Innovation Solution

A heterocyclic compound with a novel structure, represented by Formula 1, is introduced, which improves internal quantum efficiency and is used in the organic light-emitting device's emission layer, hole transport region, or electron transport region, enhancing charge transport capabilities and exciton formation.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If conventional organic light-emitting devices are used, then device structure is simple, but internal quantum efficiency and luminance are limited

Engineering Contradiction:
Improveinternal quantum efficiencyVSAvoiddevice structure
Core Design Contradiction:
ProductivityVSDevice complexity

Solution Approach 1:

The patent introduces a novel heterocyclic compound with specific molecular structure (Formula 1) that changes the chemical and physical parameters of the emission layer, resulting in improved internal quantum efficiency and luminance without fundamentally altering the device architecture

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs a composite material approach by combining the heterocyclic compound with specific substituents (R1-R4) and heteroatomic groups (X1, L1) to create a material with optimized charge transport and exciton formation properties, achieving high efficiency while maintaining device simplicity

Inventive Principle:
Principle #40Composite materials

2Reliability

If conventional emission layer materials are used, then device manufacturing is easy, but charge transport capabilities and exciton formation ratios are suboptimal

Engineering Contradiction:
Improvecharge transport capabilitiesVSAvoidemission layer fabrication
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The heterocyclic compound modifies key parameters including charge mobility, exciton formation ratio, and HOMO-LUMO energy levels, enabling superior charge transport and exciton generation while maintaining compatibility with conventional fabrication processes

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent introduces specific local structural features in the heterocyclic compound (such as the heteroatomic group X1 and linker L1) that locally enhance charge transport and exciton formation properties without requiring changes to the overall device structure or manufacturing process

Inventive Principle:
Principle #3Local quality

3Illumination intensity

If high luminance and long lifespan are achieved, then driving voltage increases, but efficiency decreases

Engineering Contradiction:
ImproveluminanceVSAvoiddriving voltage
Core Design Contradiction:
Illumination intensityVSUse of energy by moving object

Solution Approach 1:

The heterocyclic compound optimizes the energy parameters of the emission layer, including HOMO and LUMO levels, to reduce the energy barrier for charge injection and transport, thereby achieving high luminance at low driving voltage with improved overall efficiency

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent replaces conventional charge transport mechanisms with enhanced exciton-mediated charge generation and transport through the heterocyclic compound, reducing reliance on high electric fields and enabling efficient operation at lower voltages

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The heterocyclic compound improves the organic light-emitting device's luminance, reduces driving voltage, and extends its lifespan by enhancing charge transport and exciton formation, resulting in high efficiency and low driving voltage.

Implementation Method 1

enhancing charge transport capabilities

Methodology Applied
Scientific EffectCharge transport: Conduction (electrical)

Implementation Method 2

Carriers, such as holes and electrons, recombine in the emission layer to produce excitons. These excitons transition from an excited state to a ground state, thereby generating light.

Methodology Applied
Scientific EffectElectroluminescence: Electroluminescence

Data Source

PatentUS11538999B2Heterocyclic compound and organic light-emitting device including the same
Publication Date: 2022.12.27 SAMSUNG DISPLAY CO LTD
  • US11538999B2 patent drawing
  • US11538999B2 patent drawing
  • US11538999B2 patent drawing

AI summary

A heterocyclic compound and an organic light-emitting device including the same are provided. The heterocyclic compound is represented by Formula 1:Details of R1, R2, R3, X1, L1, and a1 and b1 are provided in the disclosure.