Heterocyclic Compounds for OLED Efficiency and Stability

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Solution Overview

Problem

Existing organic electronic devices, such as OLEDs, face challenges in achieving high energy efficiency, low operating voltage, long lifetime, and broad temperature stability, with current materials lacking in processability and solubility for efficient film formation.

Innovation Solution

Development of novel heterocyclic compounds with specific structures, including fluorene and carbazole derivatives, which serve as electron blocker, hole transport, and matrix materials, enhancing efficiency, voltage, and lifetime, and allowing for simple processing and good solubility, thereby improving the performance of organic electronic devices across a wide temperature range.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Use of energy by moving object

If conventional organic semiconductor materials are used in electronic devices, then device structure and function can be achieved, but energy efficiency is insufficient and operating voltage is high

Engineering Contradiction:
Improveenergy efficiencyVSAvoidoperating voltage
Core Design Contradiction:
Use of energy by moving objectVSPower

Solution Approach 1:

The patent applies parameter changes by systematically modifying molecular structures of organic semiconductors, including changing heterocyclic rings, substituent groups, and molecular weight parameters to optimize energy efficiency and reduce operating voltage in electronic devices

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs composite materials by combining different organic semiconductor components with complementary properties, creating multi-component systems that achieve both high energy efficiency and low operating voltage through synergistic effects

Inventive Principle:
Principle #40Composite materials

2Duration of action of stationary object

If conventional organic semiconductor materials are used, then basic device functionality is achieved, but device lifetime is limited

Engineering Contradiction:
Improvedevice lifetimeVSAvoidperformance stability
Core Design Contradiction:
Duration of action of stationary objectVSReliability

Solution Approach 1:

The patent extends device lifetime by optimizing material parameters including molecular weight, glass transition temperature, and thermal stability parameters, ensuring reliable performance over extended operational periods

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent implements beforehand cushioning by selecting materials with high thermal and chemical stability margins that provide a buffer against degradation, maintaining performance stability under varying operational conditions and extending device lifetime

Inventive Principle:
Principle #11Beforehand cushioning (Prior cushioning)

3Ease of manufacture

If conventional organic semiconductor materials are used, then device performance can be achieved, but solubility and processability are poor

Engineering Contradiction:
ImproveprocessabilityVSAvoidfilm formation quality
Core Design Contradiction:
Ease of manufactureVSManufacturing precision

Solution Approach 1:

The patent improves processability by changing material parameters including introducing solubilizing side chains, adjusting molecular weight distribution, and modifying crystallinity parameters to enable high-quality film formation through solution processing techniques

Inventive Principle:
Principle #35Parameter changes

4Stability of the object's composition

If conventional organic semiconductor materials are used, then basic electronic function is achieved, but temperature stability is insufficient

Engineering Contradiction:
Improvetemperature stabilityVSAvoidtemperature range performance
Core Design Contradiction:
Stability of the object's compositionVSAdaptability or versatility

Solution Approach 1:

The patent achieves temperature stability by optimizing material parameters including glass transition temperature, thermal decomposition temperature, and phase transition parameters, enabling devices to maintain performance across broad temperature ranges

Inventive Principle:
Principle #35Parameter changes

Data Source

PatentUS10957859B2Heterocyclic compounds for use in electronic devices
Publication Date: 2021.03.23 MERCK PATENT GMBH
  • US10957859B2 patent drawing
  • US10957859B2 patent drawing
  • US10957859B2 patent drawing

AI summary

The present invention relates to heterocyclic compounds and to electronic devices, especially organic electroluminescent devices, comprising these compounds.