Heterocyclic Compounds for OLED Device Performance

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Solution Overview

Problem

There is a need for heterocyclic compounds that can improve the performance of organic electroluminescent devices in terms of service life, color purity, efficiency, and operating voltage, while also offering excellent processability and solubility, particularly as emitters or matrix materials for red, green, and blue devices.

Innovation Solution

The development of specific heterocyclic compounds with structures such as those represented by formulas (IIa) to (Ile), (III-1) to (III-25), and (IV-1) to (IV-38), which include aromatic and heteroaromatic ring systems, are used in organic electroluminescent devices to enhance their performance as emitters or matrix materials.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional phosphorescent organometallic complexes or fluorescent compounds are used as emitting materials, then the devices can achieve basic electroluminescence function, but the service life, color purity, efficiency, and operating voltage remain suboptimal

Engineering Contradiction:
Improveservice lifeVSAvoidcompound structure complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The heterocyclic compounds are divided into specific structural units (formula IIa-IIe) with defined heteroatom positions and aromatic ring systems, allowing systematic optimization of device performance while maintaining manageable structural complexity

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The patent optimizes specific parameters of the heterocyclic compounds including the type and position of heteroatoms (N, O, S), the number of aromatic rings (6-40 C atoms), and substitution patterns to achieve improved service life, color purity, efficiency, and operating voltage

Inventive Principle:
Principle #35Parameter changes

2Manufacturing precision

If heterocyclic compounds with improved performance are developed, then color purity and efficiency are enhanced, but the complexity of compound synthesis and processing increases

Engineering Contradiction:
Improvecolor purityVSAvoidprocessability
Core Design Contradiction:
Manufacturing precisionVSEase of manufacture

Solution Approach 1:

The patent introduces specific local structural features (heteroatoms at defined positions, particular aromatic ring configurations) that locally enhance color purity and efficiency without requiring complete redesign of the entire molecular structure, thus maintaining ease of manufacture

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The heterocyclic compounds combine multiple functional units (aromatic rings, heteroatoms, substitution groups) into a composite molecular structure that achieves superior color purity and efficiency while retaining processability through established synthesis methods

Inventive Principle:
Principle #40Composite materials

3Productivity

If compounds with enhanced device performance are used, then efficiency and color purity improve, but the operating voltage and cost considerations become more challenging

Engineering Contradiction:
Improvedevice efficiencyVSAvoidoperating voltage
Core Design Contradiction:
ProductivityVSUse of energy by stationary object

Solution Approach 1:

The patent systematically adjusts molecular parameters (heteroatom type, aromatic ring count, substitution patterns) to optimize the balance between device efficiency and operating voltage, achieving enhanced productivity without excessive energy consumption

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

These compounds lead to organic electroluminescent devices with improved lifespan, color purity, efficiency, and reduced operating voltage, maintaining performance across a wide temperature range and offering cost-effective and consistent quality.

Implementation Method 1

In organic electroluminescent devices, phosphorescent organometallic complexes or fluorescent compounds are often used as emitting materials

Methodology Applied
Scientific EffectElectroluminescence: Electroluminescence

Data Source

PatentEP4122028B1Heterocyclic compounds for organic electroluminescent devices
Publication Date: 2024.10.16 MERCK PATENT GMBH
  • EP4122028B1 patent drawing
  • EP4122028B1 patent drawing
  • EP4122028B1 patent drawing

AI summary

The invention relates to heterocyclic compounds which are suitable for use in electronic devices, and to electronic devices, in particular organic electroluminescent devices, containing said compounds.