Heterocyclic Compound Emission Layer for Light-Emitting Devices

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Solution Overview

Problem

Current light-emitting devices face limitations in achieving high luminescence efficiency, low driving voltage, and long lifespan due to inadequate charge transport and stability in their emission layers.

Innovation Solution

Incorporation of a heterocyclic compound represented by Formula 1, which includes a 5-membered to 10-membered saturated cyclic group, into the light-emitting device's interlayer, enhancing charge transport and stability, thereby improving luminescence efficiency and device lifespan.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If conventional emission layers are used in light-emitting devices, then device structure is simple, but luminescence efficiency is insufficient and lifespan is limited

Engineering Contradiction:
Improveluminescence efficiencyVSAvoidemission layer composition
Core Design Contradiction:
ProductivityVSDevice complexity

Solution Approach 1:

The emission layer uses a composite system consisting of a host compound and a heterocyclic compound (Formula 1). The host compound provides structural framework while the heterocyclic compound acts as dopant to enhance charge transport and luminescence efficiency. This composite approach allows achieving high luminescence efficiency without significantly complicating the device structure.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The heterocyclic compound is specifically designed with local functional groups: a 5-membered to 10-membered saturated cyclic group for stability, heterocyclic rings for charge transport, and adjustable substituent groups (R1-R10) for optimizing luminescence properties. This local quality optimization enables tailored performance enhancement in specific regions of the emission layer.

Inventive Principle:
Principle #3Local quality

2Productivity

If emission layers with adequate charge transport are used, then luminescence efficiency improves, but driving voltage increases

Engineering Contradiction:
Improveluminescence efficiencyVSAvoiddriving voltage
Core Design Contradiction:
ProductivityVSPower

Solution Approach 1:

The heterocyclic compound employs adjustable parameters including the type of saturated cyclic group (5-10 membered rings), the specific heterocyclic rings (ring CY2-CY5), and substituent groups (R1-R10). By optimizing these parameters, the compound achieves balanced charge transport capability and appropriate energy levels that facilitate efficient carrier recombination at lower driving voltages.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent provides numerous specific embodiments (Compounds 1-147) that replicate the successful structural pattern of Formula 1 with varying substituents. These copied structures have been optimized to achieve the desired balance between charge transport and driving voltage through systematic variation of R1-R10 groups while maintaining the core heterocyclic framework.

Inventive Principle:
Principle #26Copying

3Duration of action of stationary object

If emission layers with enhanced stability are used, then device lifespan extends, but charge transport capability may be reduced

Engineering Contradiction:
Improvedevice lifespanVSAvoidcharge transport
Core Design Contradiction:
Duration of action of stationary objectVSSpeed

Solution Approach 1:

The heterocyclic compound incorporates specific local structural features: the 5-membered to 10-membered saturated cyclic group (ring CY1) provides steric bulk and structural stability to prevent degradation, while the heterocyclic rings (ring CY2-CY5) with appropriate π-conjugation maintain charge transport pathways. The local quality of each structural element is optimized to fulfill its specific function without compromising the other.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The compound combines stabilizing saturated cyclic groups with charge-transporting heterocyclic rings in a single molecular structure. This intramolecular composite design ensures that stability and charge transport capabilities are integrated at the molecular level, allowing the emission layer to maintain both properties simultaneously during device operation.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The use of the heterocyclic compound in the light-emitting device leads to improved luminescence efficiency, reduced driving voltage, and extended lifespan by stabilizing the emission layer and enhancing charge transport.

Implementation Method 1

enhancing charge transport and stability, thereby improving luminescence efficiency and device lifespan

Methodology Applied
Scientific EffectCharge transport: Conduction (electrical)

Implementation Method 2

Carriers, such as holes and electrons, recombine in the emission layer to produce excitons. These excitons transition from an excited state to a ground state to thereby generate light.

Methodology Applied
Scientific EffectExciton stabilization:

Implementation Method 3

reduced driving voltage, and extended lifespan by stabilizing the emission layer and enhancing charge transport

Methodology Applied
Scientific EffectEnergy level alignment:

Data Source

PatentUS20230180595A1Light-emitting device including heterocyclic compound and electronic apparatus including light-emitting device
Publication Date: 2023.06.08 SAMSUNG DISPLAY CO LTD
  • US20230180595A1 patent drawing
  • US20230180595A1 patent drawing
  • US20230180595A1 patent drawing

AI summary

A light-emitting device is provided and including a heterocyclic compound represented by Formula 1, and an electronic apparatus including the light-emitting device:Formula 1 may be understood by referring to the description of Formula 1 provided herein.