Heterocyclic Compound Emission Layer for OLED Efficiency

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Solution Overview

Problem

Current light-emitting devices, particularly OLEDs, face limitations in luminescence efficiency and driving voltage, which affect their performance and lifespan.

Innovation Solution

Incorporation of heterocyclic compounds with specific structures, such as those represented by Formula 1, into the emission layer of light-emitting devices to enhance luminescence efficiency and energy transfer, combined with fluorescent and phosphorescent dopants to improve efficiency and lifespan characteristics.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Use of energy by moving object

If conventional emission layer materials are used, then device structure is simple, but luminescence efficiency is low and driving voltage is high

Engineering Contradiction:
Improveluminescence efficiencyVSAvoiddriving voltage
Core Design Contradiction:
Use of energy by moving objectVSPower

Solution Approach 1:

The patent modifies the molecular structure parameters of emission layer materials by introducing specific heterocyclic groups (triazine, pyrimidine, pyridine rings) and adjusting substituents to optimize HOMO-LUMO energy levels, thereby improving luminescence efficiency while reducing driving voltage

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs composite emission layer materials combining heterocyclic compounds with fluorescent and phosphorescent dopants to achieve synergistic effects that enhance luminescence efficiency and reduce operating voltage simultaneously

Inventive Principle:
Principle #40Composite materials

2Duration of action of stationary object

If conventional emission layer materials are used, then device structure is simple, but lifespan is short

Engineering Contradiction:
ImprovelifespanVSAvoidcompound structure complexity
Core Design Contradiction:
Duration of action of stationary objectVSDevice complexity

Solution Approach 1:

The patent adjusts molecular weight, steric hindrance parameters, and chemical stability parameters of emission layer compounds to enhance device lifespan while managing structural complexity through systematic molecular design

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent develops small molecule heterocyclic compounds that can be precisely synthesized and optimized for extended device lifespan, replacing less stable conventional materials with tailored molecular structures

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

3Quantity of substance

If conventional emission layer materials are used, then current consumption is high, but material selection is simple

Engineering Contradiction:
Improvecurrent consumptionVSAvoidmaterial selection flexibility
Core Design Contradiction:
Quantity of substanceVSAdaptability or versatility

Solution Approach 1:

The patent optimizes charge transport parameters and energy level alignment in emission layer materials to reduce current consumption while maintaining flexibility in material selection through systematic variation of heterocyclic substituents

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The use of these heterocyclic compounds results in light-emitting devices with low driving voltage, high maximum quantum yield, and long lifespan, while reducing current at the same luminance.

Implementation Method 1

a structure which enables electrons in an emission layer to be adjusted to be advantageous for luminescence efficiency and energy transfer

Methodology Applied
Scientific EffectEnergy transfer:

Implementation Method 2

significant and unexpectedly excellent luminescence efficiency

Methodology Applied
Scientific EffectLuminescence: Luminescence

Implementation Method 3

The emission layer may include a first compound, and the first compound may be a fluorescent compound

Methodology Applied
Scientific EffectFluorescence: Fluorescence

Implementation Method 4

combined with fluorescent and phosphorescent dopants to improve efficiency and lifespan characteristics

Methodology Applied
Scientific EffectPhosphorescence: Phosphorescence

Data Source

PatentUS20220246860A1Heterocyclic compound, a light-emitting device including the same, and an electronic apparatus including the light-emitting device
Publication Date: 2022.08.04 SAMSUNG DISPLAY CO LTD
  • US20220246860A1 patent drawing
  • US20220246860A1 patent drawing
  • US20220246860A1 patent drawing

AI summary

A light-emitting device includes: a first electrode; a second electrode facing the first electrode; an interlayer between the first electrode and the second electrode and including an emission layer; and at least one heterocyclic compound of Formula 1, as defined herein. The light-emitting device further includes Formulas 2-1 or 2-2, and 3-1 or 3-2, as defined herein.