Heterocyclic Host Composition for Low-Voltage Blue OLED Emission

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Solution Overview

Problem

Organic light-emitting devices (OLEDs) face challenges in achieving low driving voltage and high emission efficiency, which are crucial for improving their performance and efficiency in electronic applications.

Innovation Solution

A heterocyclic compound represented by Formula 1 is used in the light-emitting device, specifically in the emission layer, which includes a dopant and a host, where the heterocyclic compound serves as the host, facilitating blue light emission and optimizing the device's operational characteristics.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Use of energy by moving object

If conventional OLED materials are used, then the device structure is simple, but the driving voltage is high and emission efficiency is low

Engineering Contradiction:
Improveemission efficiencyVSAvoiddriving voltage
Core Design Contradiction:
Use of energy by moving objectVSPower

Solution Approach 1:

The patent modifies the molecular structure of the host material by introducing specific heterocyclic groups (triazine, pyrimidine, pyridine rings) and adjusting substituent positions (d1, d2, d3, d4, d11, d12 parameters), which changes the electronic and optical properties to achieve lower driving voltage and higher emission efficiency

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates composite OLED structures by combining the heterocyclic host material with specific dopants (iridium complexes, platinum complexes, or delayed fluorescent dopants) to form an emission layer that simultaneously achieves low driving voltage and high emission efficiency through synergistic effects

Inventive Principle:
Principle #40Composite materials

2Use of energy by moving object

If conventional host materials are used, then the emission layer is simple, but the luminescence efficiency is low

Engineering Contradiction:
Improveluminescence efficiencyVSAvoidemission layer structure
Core Design Contradiction:
Use of energy by moving objectVSDevice complexity

Solution Approach 1:

The patent introduces specific functional groups at localized positions in the heterocyclic molecule (different Ar1-Ar4 substituents at different positions) to optimize local electronic properties, enabling high luminescence efficiency while maintaining a relatively simple overall molecular structure

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The heterocyclic host material acts as an intermediary between the dopant and the charge carriers, facilitating efficient energy transfer and charge recombination to achieve high luminescence efficiency. The host material mediates the interaction between electrons and holes, enabling effective exciton generation and light emission

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The use of the heterocyclic compound in the OLEDs results in a light-emitting device with improved driving voltage and luminescence efficiency, enhancing the overall performance and efficiency of the electronic apparatus.

Implementation Method 1

Carriers, such as holes and electrons, recombine in the emission layer to produce excitons. These excitons transit from an excited state to a ground state to thereby generate light.

Methodology Applied
Scientific EffectElectroluminescence: Electroluminescence

Data Source

PatentUS12193320B2Heterocyclic compound, light-emitting device including heterocyclic compound, and electronic apparatus including light-emitting device
Publication Date: 2025.01.07 SAMSUNG DISPLAY CO LTD
  • US12193320B2 patent drawing
  • US12193320B2 patent drawing
  • US12193320B2 patent drawing

AI summary

A heterocyclic compound represented by Formula 1:wherein, in Formula 1, Ar1 to Ar4, Ar11, and Ar12 are each, independently from one another, as defined herein.