Heterocyclic Compound for OLED Electron Transport

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Solution Overview

Problem

Conventional organic light-emitting diodes (OLEDs) face challenges in achieving improved electrical stability, high charge-transferring and light-emitting abilities, preventing crystallization, and maintaining efficiency over time.

Innovation Solution

A heterocyclic compound with a specific chemical structure, represented by Formula 1, is used as an electron-transporting or electron-injecting material in OLEDs, enhancing electrical properties and preventing crystallization, thereby improving the efficiency and longevity of OLEDs.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional OLED materials are used, then the device structure is simple, but electrical stability and charge-transferring ability are insufficient

Engineering Contradiction:
Improveelectrical stabilityVSAvoidmaterial structure complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent modifies the molecular structure parameters of OLED materials by introducing specific heterocyclic groups (triazole, tetrazole, oxadiazole, etc.) and substituent patterns in Formula 1, which changes the electrical properties and charge-transferring ability while maintaining structural feasibility for device fabrication

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention creates composite molecular structures by combining electron-transporting heterocyclic cores with various aryl, heteroaryl, and condensed polycyclic groups, achieving enhanced electrical stability and charge-transferring ability through the synergistic effects of different structural components

Inventive Principle:
Principle #40Composite materials

2Productivity

If conventional OLED materials are used, then manufacturing is easier, but light-emitting ability and efficiency are insufficient

Engineering Contradiction:
Improvelight-emitting efficiencyVSAvoidmaterial synthesis difficulty
Core Design Contradiction:
ProductivityVSEase of manufacture

Solution Approach 1:

The patent divides the OLED material into functional segments: a core heterocyclic electron-transporting unit (triazole, tetrazole, oxadiazole, etc.) and substituent groups (aryl, heteroaryl, condensed polycyclic), allowing independent optimization of light-emitting properties while maintaining manufacturability through modular synthesis approaches

Inventive Principle:
Principle #1Segmentation

3Duration of action of stationary object

If conventional OLED materials are used, then initial performance is acceptable, but crystallization occurs and lifetime is reduced

Engineering Contradiction:
ImproveOLED lifetimeVSAvoidcrystallization resistance
Core Design Contradiction:
Duration of action of stationary objectVSStability of the object's composition

Solution Approach 1:

The patent introduces specific local structural features (heterocyclic rings with nitrogen/oxygen atoms, substituted aryl groups, condensed polycyclic systems) that create localized regions with different packing behaviors, preventing crystallization while maintaining long-term operational stability and extended OLED lifetime

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The heterocyclic compound enables the production of OLEDs with high efficiency, low driving voltage, high luminance, and extended lifespan, suitable for various color emissions.

Implementation Method 1

electrons injected from the cathode move to the EML via the ETL

Methodology Applied
Scientific EffectElectron transport: Conduction (electrical)

Implementation Method 2

electrons injected from the cathode move to the EML via the ETL

Methodology Applied
Scientific EffectElectron injection: Thermionic Emission

Implementation Method 3

The compound, which is a material having a high glass transition temperature and that is capable of preventing crystallization

Methodology Applied
Scientific EffectCrystallization prevention: Vitrification

Implementation Method 4

The holes and electrons (carriers) recombine in the EML to generate excitons. When the excitons drop from an excited state to a ground state, light is emitted

Methodology Applied
Scientific EffectElectroluminescence: Electroluminescence

Data Source

PatentUS9391282B2Heterocyclic compound and organic light-emitting diode including the same
Publication Date: 2016.07.12 SAMSUNG DISPLAY CO LTD
  • US9391282B2 patent drawing
  • US9391282B2 patent drawing
  • US9391282B2 patent drawing

AI summary

A heterocyclic compound is represented by Formula 1. The heterocyclic compound may be used in an organic layer of an organic light-emitting diode. An organic light-emitting diode includes a first electrode, a second electrode and an organic layer, and the organic layer includes the heterocyclic compound represented by Formula 1. The organic light-emitting diode may be used in a flat panel display device, in which the first electrode of the organic light-emitting diode may be electrically connected to a source or drain electrode of a thin film transistor.