Heterocyclic OLED Material for Low-Voltage Charge Balance

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Solution Overview

Problem

There is a need for new materials in organic light emitting devices to enhance efficiency and stability, particularly in achieving low driving voltage and improving lifetime characteristics.

Innovation Solution

A novel compound represented by Chemical Formula 1 or 2 is introduced, which can be used as a material for various organic material layers, including hole injection, transport, emission, and injection layers, improving the efficiency and lifetime of organic light emitting devices.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If conventional organic materials are used in organic light emitting devices, then the device structure can be maintained, but the efficiency is insufficient and the driving voltage is high

Engineering Contradiction:
Improvedevice efficiencyVSAvoiddriving voltage
Core Design Contradiction:
ProductivityVSUse of energy by moving object

Solution Approach 1:

The patent modifies the molecular structure parameters of organic materials by introducing specific heterocyclic groups (X1-X3 where at least one is N) and substituent groups (Ar1, Ar2, R1) in defined positions, which changes the electronic properties and charge transport characteristics of the material, thereby improving efficiency and reducing driving voltage

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates composite organic material structures by combining multiple functional groups (heterocyclic core with aryl and heteroaryl substituents) into a single molecule, where each component contributes specific properties that collectively enhance device performance

Inventive Principle:
Principle #40Composite materials

2Duration of action of stationary object

If conventional organic materials are used, then material availability is maintained, but lifetime characteristics are insufficient

Engineering Contradiction:
Improvedevice lifetimeVSAvoidstability
Core Design Contradiction:
Duration of action of stationary objectVSReliability

Solution Approach 1:

The patent changes the chemical stability parameters by incorporating nitrogen-containing heterocyclic rings and stable aryl/heteroaryl groups, which increase the material's resistance to degradation and improve operational lifetime and reliability

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent uses deuterium substitution in some embodiments, which extends material lifetime by reducing isotopic exchange reactions that lead to degradation, effectively creating more stable versions of the organic materials

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

3Productivity

If new heterocyclic compounds are introduced to improve efficiency, then device performance increases, but the complexity of material synthesis increases

Engineering Contradiction:
Improvedevice efficiencyVSAvoidsynthesis complexity
Core Design Contradiction:
ProductivityVSEase of manufacture

Solution Approach 1:

The patent designs molecules with modular segments (heterocyclic core, aryl substituents, heteroaryl groups) that can be synthesized separately and then assembled through established coupling reactions, reducing overall synthesis complexity while maintaining advanced functionality

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The patent creates universal heterocyclic core structures that can serve multiple functions (charge transport, hole injection, electron transport) depending on the substituents attached, allowing a single core structure to be used for various device layers and applications

Inventive Principle:
Principle #6Universality (Multi-functionality)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The compound improves the efficiency and reduces the driving voltage while enhancing the lifetime of organic light emitting devices by facilitating effective charge transfer and balancing charges within the device layers.

Implementation Method 1

an organic light emitting phenomenon refers to a phenomenon where electrical energy is converted into light energy by using an organic material

Methodology Applied
Scientific EffectElectroluminescence: Electroluminescence

Data Source

PatentUS11746117B2Heterocyclic compound and organic light emitting device comprising same
Publication Date: 2023.09.05 LG CHEM LTD
  • US11746117B2 patent drawing
  • US11746117B2 patent drawing
  • US11746117B2 patent drawing

AI summary

A heterocyclic compound represented by Chemical Formula 1 or 2, and an organic light emitting device including the same, and the heterocyclic compound which is used as a material of an organic material layer of the organic light emitting device and provides improved efficiency, low driving voltage, and improved lifetime characteristics of the organic light emitting device.