Heterocyclic Compound for OLED Hole Injection and Transport

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Solution Overview

Problem

Current organic light-emitting diodes (OLEDs) face challenges in achieving optimal hole injection and transport capabilities, leading to inefficiencies in light emission and stability, particularly in multi-color displays.

Innovation Solution

A heterocyclic compound represented by Formula 1 is used in the organic layer of OLEDs, which includes various substituents and linking groups to enhance hole injection and transport capabilities, improving the efficiency and stability of the diodes.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If conventional organic materials are used in OLEDs, then the device structure can be maintained, but hole injection and transport capabilities are insufficient leading to efficiency losses

Engineering Contradiction:
Improvelight emission efficiencyVSAvoidhole injection capability
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The patent modifies the chemical structure of organic compounds by introducing specific heterocyclic groups (triazine, pyrimidine, pyridine rings) and substituent patterns to optimize electronic properties. This changes the molecular parameters such as HOMO/LUMO energy levels, carrier mobility, and glass transition temperature to simultaneously improve hole injection capability and light emission efficiency

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs composite organic layer structures combining multiple heterocyclic compounds with different functional characteristics. The organic layer includes host materials, guest dopants, and auxiliary compounds that work synergistically to enhance both charge transport and light emission properties, resolving the contradiction between injection capability and emission efficiency

Inventive Principle:
Principle #40Composite materials

2Illumination intensity

If OLEDs operate at high brightness, then display quality improves, but driving voltage increases and lifespan decreases

Engineering Contradiction:
ImprovebrightnessVSAvoiddevice lifespan
Core Design Contradiction:
Illumination intensityVSDuration of action of stationary object

Solution Approach 1:

The patent optimizes the energy level parameters of organic materials to reduce the energy gap between HOMO and LUMO states. This enables more efficient electron-hole recombination at lower voltages, allowing high brightness operation without excessive voltage that would otherwise accelerate material degradation and reduce lifespan

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent uses stable heterocyclic organic compounds that resist oxidation and degradation, effectively creating longer-lived active materials. The robust molecular structures with aromatic rings and heteroatoms provide resistance against chemical degradation, allowing the OLED to maintain performance over extended periods even at high brightness

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

3Adaptability or versatility

If multi-color displays are implemented, then display versatility improves, but color purity and stability become difficult to maintain

Engineering Contradiction:
Improvemulti-color capabilityVSAvoidcolor stability
Core Design Contradiction:
Adaptability or versatilityVSReliability

Solution Approach 1:

The patent divides the OLED structure into separate functional layers including distinct hole transport layers, electron transport layers, and emission layers. Each layer uses specialized heterocyclic compounds optimized for its specific function, allowing independent optimization of color emission properties while maintaining overall device stability and color purity

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The patent employs host-guest systems where host materials act as intermediaries that facilitate energy transfer to guest dopant molecules. This intermediary mechanism enables precise color control through dopant selection while the host material maintains structural stability and charge transport, resolving the conflict between color versatility and stability

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The use of the heterocyclic compound in OLEDs results in improved hole injection and transport capabilities, leading to higher efficiency, longer lifespan, and reduced driving voltage, making them suitable for multi-color displays.

Implementation Method 1

enhance hole injection and transport capabilities

Methodology Applied
Scientific EffectCharge transport: Conduction (electrical)

Implementation Method 2

organic light-emitting diodes (OLEDs), which are self-emitting diodes

Methodology Applied
Scientific EffectElectroluminescence: Electroluminescence

Data Source

PatentUS9627634B2Heterocyclic compound and organic light-emitting diode including the same
Publication Date: 2017.04.18 SAMSUNG DISPLAY CO LTD
  • US9627634B2 patent drawing
  • US9627634B2 patent drawing
  • US9627634B2 patent drawing

AI summary

Provided is a heterocyclic compound represented by Formula 1 and an organic light-emitting diode including the same: