Heterocyclic Matrix Compounds for OLED Efficiency and Lifetime

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Solution Overview

Problem

Current organic electroluminescent devices, particularly those exhibiting phosphorescence, face limitations in efficiency, operating voltage, and service life, with existing matrix materials not adequately addressing these issues.

Innovation Solution

Development of specific heterocyclic compounds that serve as matrix materials in organic electroluminescent devices, enhancing efficiency, reducing operating voltage, and extending service life, while also being easy to process and exhibit good solubility and film formation properties.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Use of energy by moving object

If organometallic complexes showing phosphorescence are used as emitting materials, then energy efficiency and power efficiency are improved (up to four times), but service life and operating voltage still require improvement

Engineering Contradiction:
Improveenergy efficiencyVSAvoidservice life
Core Design Contradiction:
Use of energy by moving objectVSDuration of action of moving object

Solution Approach 1:

The patent applies parameter changes by developing new heterocyclic compounds with specific molecular structures (formulas I and II) that modify the electronic and physical parameters of the emitting layer. These structural modifications enable simultaneous improvement of service life and efficiency by optimizing charge transport, exciton management, and material stability in the OLED device

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs composite materials by combining heterocyclic compounds with carbazole structures and triazine or pyrimidine derivatives to create hybrid matrix materials. These composite structures integrate the advantages of both component types, achieving enhanced service life, efficiency, and voltage characteristics that neither material alone could provide

Inventive Principle:
Principle #40Composite materials

2Reliability

If aromatic or heteroaromatic compounds such as triarylamine or carbazole derivatives are used as matrix materials, then device functionality is achieved, but service life, efficiency, and operating voltage require improvement

Engineering Contradiction:
Improveservice lifeVSAvoidmaterial structure complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent modifies material parameters by designing heterocyclic compounds with specific molecular weights (500-3000 Da) and defined structural features. These parameter optimizations improve service life and efficiency while maintaining processability and avoiding excessive structural complexity

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent applies local quality by incorporating specific functional groups (carbazole, triazine, pyrimidine) at targeted positions within the molecular structure. This localized functionalization optimizes specific device performance aspects (charge transport, stability) without requiring complete structural redesign

Inventive Principle:
Principle #3Local quality

3Productivity

If compounds are designed for excellent device performance, then efficiency and service life improve, but processing ease, solubility, and film formation may be compromised

Engineering Contradiction:
Improvedevice efficiencyVSAvoidprocessing ease
Core Design Contradiction:
ProductivityVSEase of manufacture

Solution Approach 1:

The patent optimizes processing parameters by controlling molecular weight (500-3000 Da) and introducing appropriate substituent groups that enhance solubility in common organic solvents. These parameter adjustments enable solution-based processing methods while maintaining high device efficiency and performance characteristics

Inventive Principle:
Principle #35Parameter changes

4Use of energy by moving object

If compounds are optimized for room temperature performance, then efficiency is improved, but performance consistency across wide temperature ranges may be compromised

Engineering Contradiction:
Improveenergy efficiencyVSAvoidtemperature range adaptability
Core Design Contradiction:
Use of energy by moving objectVSAdaptability or versatility

Solution Approach 1:

The patent enhances temperature adaptability by modifying molecular structure parameters to improve thermal stability and glass transition temperature. These structural modifications enable the material to maintain consistent efficiency and performance characteristics across wide temperature ranges from -40°C to +85°C

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The use of these heterocyclic compounds significantly improves the performance of organic electroluminescent devices by enhancing efficiency, reducing operating voltage, and extending service life, while maintaining performance across a wide temperature range and being cost-effective.

Implementation Method 1

compounds suitable for use in an organic electronic device, in particular in organic electroluminescence devices... compounds that lead to a long lifetime, good efficiency, and low operating voltage

Methodology Applied
Scientific EffectElectron transport: Conduction (electrical)

Implementation Method 2

Metal-organic complexes exhibiting phosphorescence are frequently used as emitting materials. Due to quantum mechanical reasons, using metal-organic compounds as phosphor emitters allows for up to four times the energy and power efficiency

Methodology Applied
Scientific EffectPhosphorescence: Phosphorescence

Implementation Method 3

organic electroluminescent devices (OLEDs) that utilize organic semiconductors as functional materials... Metal-organic complexes exhibiting phosphorescence are frequently used as emitting materials

Methodology Applied
Scientific EffectElectroluminescence: Electroluminescence

Data Source

PatentEP3548481B1Heterocyclic compounds for use in electronic devices
Publication Date: 2023.08.23 MERCK PATENT GMBH
  • EP3548481B1 patent drawing
  • EP3548481B1 patent drawing
  • EP3548481B1 patent drawing

AI summary

The invention relates to heterocyclic compounds, particularly for use in electronic devices. The invention further relates to a method for producing the compounds according to the invention, and to electronic devices comprising same.