Heterocyclic Compounds for OLED Matrix Materials

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Solution Overview

Problem

Current organic electroluminescent devices face challenges in achieving high lifetime, efficiency, and low operating voltage, particularly due to limitations in matrix materials used, and there is a need for materials suitable for red- and yellow-phosphorescing devices that maintain performance across a broad temperature range while ensuring cost-effectiveness and quality.

Innovation Solution

Development of specific heterocyclic compounds with defined structures that serve as matrix materials, electron transport materials, or hole blocker materials, enhancing the properties of organic electroluminescent devices by improving lifetime, efficiency, and color purity, and being suitable for use in a wide range of applications including red- and yellow-phosphorescing devices.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional matrix materials are used in phosphorescent OLEDs, then device fabrication is straightforward, but device lifetime and efficiency remain limited

Engineering Contradiction:
Improvedevice lifetimeVSAvoidmaterial selection complexity
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The patent modifies the molecular structure of matrix materials by introducing specific heterocyclic rings (triazine, pyrimidine, pyridine) and adjusting substituent groups to optimize triplet energy levels and HOMO/LUMO distributions. This parameter optimization enables improved device lifetime and efficiency while maintaining compatibility with standard fabrication processes

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention develops composite matrix materials combining electron-transporting heterocyclic structures with phosphorescent emitter compatibility. These composite materials simultaneously provide improved electron transport, optimized energy levels for phosphorescent emitters, and enhanced device stability, resolving the contradiction between performance improvement and manufacturing simplicity

Inventive Principle:
Principle #40Composite materials

2Loss of energy

If matrix materials are optimized for high efficiency, then power efficiency improves, but operating voltage increases

Engineering Contradiction:
Improvepower efficiencyVSAvoidoperating voltage
Core Design Contradiction:
Loss of energyVSStress or pressure

Solution Approach 1:

The patent introduces different functional groups at specific positions within the heterocyclic matrix structure to create local electron transport pathways. The triazine and pyrimidine rings provide localized high-electron mobility regions that reduce overall operating voltage while maintaining high power efficiency through optimized electron-hole recombination zones

Inventive Principle:
Principle #3Local quality

3Stability of the object's composition

If conventional materials are used for red- and yellow-phosphorescing devices, then device performance varies across temperature ranges, but material development costs increase

Engineering Contradiction:
Improvetemperature stabilityVSAvoidmaterial development cost
Core Design Contradiction:
Stability of the object's compositionVSEase of manufacture

Solution Approach 1:

The patent develops universal heterocyclic matrix materials with broad temperature stability that can be used across multiple phosphorescent emitter types (red, yellow, green). The core triazine-pyrimidine-pyridine scaffold provides temperature-insensitive electronic properties that maintain device performance across varying temperatures while reducing the need for emitter-specific material optimization, thereby lowering development costs

Inventive Principle:
Principle #6Universality (Multi-functionality)

Data Source

PatentUS20230416264A1Heterocyclic compounds for organic electroluminescent devices
Publication Date: 2023.12.28 MERCK PATENT GMBH
  • US20230416264A1 patent drawing
  • US20230416264A1 patent drawing
  • US20230416264A1 patent drawing

AI summary

The present invention relates to heterocyclic compounds which are suitable for use in electronic devices, and to electronic devices, in particular organic electroluminescent devices, containing said compounds.