Heterocyclic OLED Emission Layer for Faster Carrier Recombination

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Solution Overview

Problem

Existing self-emissive devices, such as organic light-emitting devices, face challenges in optimizing the performance of their emission layers to enhance luminance, driving voltage, and response speed while maintaining wide viewing angles and high contrast ratios.

Innovation Solution

Incorporation of a heterocyclic compound represented by Formula 1 into the emission layer of a light-emitting device, which includes a first and second electrode, to improve the recombination of holes and electrons, thereby enhancing the efficiency and performance of the device.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Illumination intensity

If conventional emission layer materials are used, then the device structure is simple, but the luminance and response speed are insufficient

Engineering Contradiction:
ImproveluminanceVSAvoidemission layer composition
Core Design Contradiction:
Illumination intensityVSDevice complexity

Solution Approach 1:

The emission layer employs a composite material system consisting of a host compound and a guest heterocyclic compound (Formula 1). This composite approach allows the host to provide structural framework and charge transport while the guest compound enhances luminance through its heterocyclic structure with specific substituents (R1-R6, L1, n1), achieving improved light emission without excessive complexity

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The heterocyclic compound introduces localized functional groups (carbazole, dibenzofuran, dibenzothiophene, or their combinations) at specific positions within the emission layer. These local structural modifications create regions of enhanced electron transport and exciton formation, improving luminance in specific areas while maintaining overall device structure

Inventive Principle:
Principle #3Local quality

2Power

If conventional emission layer materials are used, then the manufacturing process is simple, but the driving voltage and response speed are suboptimal

Engineering Contradiction:
Improvedriving voltageVSAvoidemission layer fabrication
Core Design Contradiction:
PowerVSEase of manufacture

Solution Approach 1:

The patent modifies molecular parameters of the emission layer materials by introducing heterocyclic compounds with specific substituent patterns (R1-R6, L1, n1). These parameter changes in molecular structure optimize charge carrier mobility and recombination energy levels, improving driving voltage and response speed while maintaining compatibility with conventional vacuum deposition manufacturing processes

Inventive Principle:
Principle #35Parameter changes

3Illumination intensity

If conventional emission layer materials are used, then the device structure is straightforward, but the viewing angles and contrast ratios are limited

Engineering Contradiction:
Improvecontrast ratioVSAvoidemission layer composition
Core Design Contradiction:
Illumination intensityVSDevice complexity

Solution Approach 1:

The composite emission layer system with host and guest compounds enables optimization of optical properties for wide viewing angles and high contrast ratios. The heterocyclic guest compound (Formula 1) with its specific heterocyclic groups creates enhanced exciton formation and light emission characteristics that improve display quality without requiring complex multi-layer structures

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The heterocyclic compound improves the luminance, driving voltage, and response speed of the light-emitting device, while maintaining wide viewing angles and high contrast ratios, thus optimizing the overall performance of the device.

Implementation Method 1

Holes provided from the first electrode move toward the emission layer through the hole transport region, while electrons provided from the second electrode move toward the emission layer through the electron transport region. These carriers, namely the holes and electrons, recombine in the emission layer to produce excitons. The excitons may transition and decay from an excited state to a ground state, thereby generating light.

Methodology Applied
Scientific EffectElectroluminescence: Electroluminescence

Data Source

PatentEP4687407A1Light-emitting device including heterocyclic compound, electronic apparatus including the light-emitting device, and the heterocyclic compound
Publication Date: 2026.02.04 SAMSUNG DISPLAY CO LTD
  • EP4687407A1 patent drawingFigure 1
  • EP4687407A1 patent drawingFigure 2
  • EP4687407A1 patent drawingFigure 3

AI summary

A light-emitting device includes a first electrode (110), a second electrode (150) opposite to the first electrode, an interlayer (130) between the first electrode and the second electrode, and a heterocyclic compound represented by Formula 1. In addition, there are provided an electronic apparatus including the light-emitting device, and the heterocyclic compound represented by Formula 1: