Heterocyclic Compound for OLED Driving Voltage and Lifetime

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Solution Overview

Problem

Current organic light emitting devices face challenges in enhancing performance, lifetime, and efficiency due to limitations in the materials used for the organic thin film, particularly in terms of hole injection, hole transfer, electron blocking, and light emission.

Innovation Solution

A heterocyclic compound represented by Chemical Formula 1 is introduced, which can serve as a material for the organic light emitting device, acting as a hole injection material, hole transfer material, light emitting material, electron transfer material, and charge generation material, thereby forming layers such as hole injection, hole transfer, light emitting, electron transfer, and electron injection layers, reducing driving voltage, enhancing light efficiency, and improving device lifetime through thermal stability.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional organic thin film materials are used, then device structure is simple, but device performance, lifetime, and efficiency are insufficient

Engineering Contradiction:
Improvedevice lifetimeVSAvoidmaterial complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The heterocyclic compound is designed to perform multiple functions simultaneously: hole injection, hole transfer, electron blocking, and light emission. This multi-functional material replaces the need for multiple separate conventional materials, thereby improving device lifetime and efficiency while maintaining reasonable structural complexity

Inventive Principle:
Principle #6Universality (Multi-functionality)

Solution Approach 2:

The patent employs a composite heterocyclic compound structure combining dibenzofuran, carbazole, and triphenylamine moieties. This composite molecular structure integrates multiple functional characteristics into a single material, achieving enhanced reliability and device performance

Inventive Principle:
Principle #40Composite materials

2Productivity

If conventional materials are used for organic thin film, then manufacturing process is simple, but hole injection and hole transfer efficiency are insufficient

Engineering Contradiction:
Improvehole transfer efficiencyVSAvoidmaterial synthesis complexity
Core Design Contradiction:
ProductivityVSEase of manufacture

Solution Approach 1:

The patent modifies molecular parameters by introducing specific heterocyclic groups (dibenzofuran, carbazole, triphenylamine) and adjusting substituent positions to optimize hole injection and transfer properties. These parameter changes enhance efficiency while maintaining synthetic feasibility through established organic synthesis methods

Inventive Principle:
Principle #35Parameter changes

3Reliability

If conventional organic thin film materials are used, then device structure is simple, but electron blocking and light emission performance are insufficient

Engineering Contradiction:
Improvelight emission efficiencyVSAvoidcompound structure complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The heterocyclic compound simultaneously provides electron blocking and light emission functions through its integrated molecular structure. The dibenzofuran-carbazole-triphenylamine framework enables both electron transport control and efficient photoluminescence, improving light emission efficiency without requiring separate functional layers

Inventive Principle:
Principle #6Universality (Multi-functionality)

Solution Approach 2:

Different regions of the heterocyclic compound molecule are optimized for specific functions: the carbazole unit contributes to hole transport, dibenzofuran provides structural rigidity and electron blocking, while triphenylamine enhances light emission. This local optimization of molecular regions achieves superior overall performance

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The heterocyclic compound improves the efficiency and stability of organic light emitting devices by lowering driving voltage, increasing light efficiency, and extending device lifetime through its thermal stability and planarity, which enhances electron transfer and bipolar properties.

Implementation Method 1

capable of performing a role of a hole injection material, a hole transfer material, a light emitting material, an electron transfer material, an electron injection material, a charge generation material

Methodology Applied
Scientific EffectCharge transfer:

Implementation Method 2

When a voltage is applied to an organic light emitting device having such a structure, electrons and holes injected from the two electrodes bind and pair in the organic thin film, and light emits as these annihilate

Methodology Applied
Scientific EffectElectroluminescence: Electroluminescence

Implementation Method 3

improving device lifetime properties can be enhanced by thermal stability of the compound

Methodology Applied
Scientific EffectThermal stability:

Data Source

PatentUS12077532B2Heterocyclic compound and organic light emitting diode comprising same
Publication Date: 2024.09.03 LT MATERIALS CO LTD
  • US12077532B2 patent drawing
  • US12077532B2 patent drawing
  • US12077532B2 patent drawing

AI summary

The present specification relates to a heterocyclic compound represented by Chemical Formula 1, and an organic light emitting device comprising the same.