Hetero-Cyclic Compound for OLED Driving Voltage and Lifetime

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

Current organic light emitting devices face challenges in enhancing performance, lifetime, and efficiency, particularly in reducing driving voltage and improving thermal stability.

Innovation Solution

Incorporation of a hetero-cyclic compound as a material for layers such as hole injection, hole transfer, light emitting, electron transfer, or charge generation in the organic light emitting device, which lowers driving voltage, enhances light efficiency, and improves thermal stability.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Duration of action of stationary object

If conventional organic thin film materials are used, then the device can operate, but the driving voltage is high and lifetime is short

Engineering Contradiction:
Improvedevice lifetimeVSAvoiddriving voltage
Core Design Contradiction:
Duration of action of stationary objectVSUse of energy by moving object

Solution Approach 1:

The patent changes the chemical structure parameters of the organic thin film material by introducing specific hetero-cyclic compounds with defined molecular structures (Formulae 1-6) containing heteroatoms (N, O, S) and specific substituents. This chemical parameter change optimizes the material's electrical and thermal properties, resulting in reduced driving voltage and extended device lifetime while maintaining operational functionality.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs composite material design by combining hetero-cyclic core structures with various substituents (R1-R6 groups) to create multifunctional organic compounds. These composite molecular structures integrate multiple functions (charge transport, hole injection, electron blocking) within a single material system, achieving both low driving voltage and high lifetime performance.

Inventive Principle:
Principle #40Composite materials

2Stability of the object's composition

If conventional organic materials are used, then the device functions, but thermal stability is insufficient

Engineering Contradiction:
Improvethermal stabilityVSAvoiddevice performance consistency
Core Design Contradiction:
Stability of the object's compositionVSReliability

Solution Approach 1:

The patent modifies the thermal stability parameter by incorporating hetero-cyclic structures with strong chemical bonds and specific molecular geometries (Formulae 1-6). The heteroatoms (N, O, S) form rigid six-membered rings that enhance thermal resistance, allowing the material to maintain structural integrity at elevated temperatures and ensuring consistent device performance over time.

Inventive Principle:
Principle #35Parameter changes

3Loss of energy

If standard organic thin film materials are used, then the device can emit light, but light efficiency is low

Engineering Contradiction:
Improvelight efficiencyVSAvoidlight output
Core Design Contradiction:
Loss of energyVSProductivity

Solution Approach 1:

The patent optimizes light efficiency by changing the optical and electronic parameters of the organic material through hetero-cyclic compound design. The molecular structures (Formulae 1-6) are engineered to achieve optimal HOMO-LUMO energy gaps and charge carrier dynamics, reducing non-radiative recombination losses and enhancing radiative recombination that produces light, thereby improving overall light efficiency and output.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The use of the hetero-cyclic compound results in reduced driving voltage, increased light efficiency, and improved thermal stability, thereby enhancing the overall performance and longevity of the organic light emitting device.

Implementation Method 1

When a voltage is applied to an organic light emitting device having such a structure, electrons and holes injected from the two electrodes bind and pair in the organic thin film, and light emits as these annihilate.

Methodology Applied
Scientific EffectElectroluminescence: Electroluminescence

Data Source

PatentEP3561892B1Organic light-emitting device
Publication Date: 2023.05.10 LT MATERIALS CO LTD
  • EP3561892B1 patent drawingFigure 1~2
  • EP3561892B1 patent drawingFigure 3
  • EP3561892B1 patent drawingFigure 4

AI summary

The present application provides a hetero-cyclic compound capable of greatly enhancing a lifetime, efficiency, electrochemical stability and thermal stability of an organic light emitting device, and an organic light emitting device containing the hetero-cyclic compound in an organic compound layer.