1,1,1,4,4,4-Hexafluoro-2-butene Insulating Medium for High-Voltage Equipment

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

Current SF6-based electrical insulation and arc-extinguishing systems have high global warming potential, necessitating a replacement with a gas that maintains similar insulating and extinguishing properties but with lower environmental impact.

Innovation Solution

A device utilizing 1,1,1,4,4-hexafluoro-2-butene as the insulating and arc-extinguishing medium, which offers high dielectric strength, effective arc suppression, and low global warming potential, combined with optional additives like fluorinated ketones and hydrofluoroolefins to enhance performance and safety.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If SF6 is used as insulating and arc-extinguishing gas, then dielectric strength and arc extinguishing properties are improved, but global warming potential increases significantly

Engineering Contradiction:
Improvedielectric strengthVSAvoidglobal warming potential
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The patent changes the chemical composition parameters by replacing SF6 with hydrofluoroolefin compounds (specifically 1,1,1,4,4,4-hexafluoro-2-butene) that have fundamentally different environmental properties. The GWP is reduced from 23,900 to below 150, while maintaining the dielectric strength through careful selection of fluorinated hydrocarbon structure and molecular properties.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs a gas with short atmospheric lifetime (rapid decomposition) compared to SF6's 3,200 year lifetime. The hydrofluoroolefin decomposes quickly in the atmosphere, effectively making it a short-living substitute that does not accumulate and cause long-term environmental harm while providing the same functional benefits.

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

2Object-affected harmful factors

If air-insulated systems are used instead of SF6, then global warming potential is reduced, but construction volume increases due to lower dielectric strength

Engineering Contradiction:
Improveglobal warming potentialVSAvoidconstruction volume
Core Design Contradiction:
Object-affected harmful factorsVSVolume of stationary object

Solution Approach 1:

The patent changes the physical and chemical parameters of the insulating medium by using fluorinated hydrocarbons with high dielectric strength. The molecular structure with multiple fluorine atoms provides electron affinity and polarization properties that maintain high dielectric strength, allowing compact design similar to SF6 systems while having minimal environmental impact.

Inventive Principle:
Principle #35Parameter changes

3Object-affected harmful factors

If solid insulation is used, then SF6 replacement is achieved, but aging and partial discharge damage become critical issues

Engineering Contradiction:
Improveenvironmental impactVSAvoidinsulation durability
Core Design Contradiction:
Object-affected harmful factorsVSReliability

Solution Approach 1:

The patent uses a gaseous insulating medium (hydrofluoroolefin) instead of solid insulation, exploiting the properties of gas to provide electrical insulation. The gas can be easily replaced and does not suffer from aging, cracking, or partial discharge damage that plagues solid insulation materials, thereby maintaining system reliability while achieving environmental goals.

Inventive Principle:
Principle #29Pneumatics and hydraulics

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution provides a more environmentally friendly alternative with improved dielectric strength, effective arc suppression, and reduced greenhouse gas emissions, suitable for high-voltage applications while maintaining reliability and safety.

Implementation Method 1

1,1,1,4,4,4-hexafluoro-2-butene has a high dielectric strength... the inventors assume that as the number of fluorine atoms in a hydrocarbon increases, its dielectric strength also increases

Methodology Applied
Scientific EffectDielectric strength: Dielectric

Implementation Method 2

These fluorine atoms are bonded to the terminal methyl groups and can accordingly prevent the onset of gas discharges, which form a precursor to dielectric breakdown, through dissociative attachment

Methodology Applied
Scientific EffectDissociative attachment: Ionisation

Data Source

PatentEP3138106B1Device and method for using 1,1,1,4,4,4-hexafluoro-2-butene as an electrically insulating and/or arc-extinguishing gaseous medium
Publication Date: 2022.04.13 SIEMENS AG
  • EP3138106B1 patent drawing
  • EP3138106B1 patent drawing
  • EP3138106B1 patent drawing

AI summary

The invention relates to a device comprising at least one electric arrangement which has an electric voltage of 1 kV or more in an operating state of the device and/or comprising at least one particle acceleration arrangement. The arrangement is at least partly arranged in a housing which contains an electrically insulating and/or arc-extinguishing gaseous medium, said medium consisting of 1,1,1,4,4,4-hexafluoro-2-butene or containing 1,1,1,4,4,4-hexafluoro-2-butene. The invention also relates to a method for using 1,1,1,4,4,4-hexafluoro-2-butene as an electrically insulating and/or arc-extinguishing gaseous medium.