HFO-1234yf Refrigerant Blend for EV Thermal Management

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Solution Overview

Problem

There is a need for low Global Warming Potential (GWP) refrigerant blends that can effectively provide both cooling and heating in hybrid, plug-in hybrid, and electric vehicles, as well as in mass transit and residential/commercial structures, while maintaining low toxicity and flammability and minimizing temperature glide for efficient thermal management.

Innovation Solution

The development of refrigerant blends comprising HFO-1234yf, HFC-152a, and HFO-1132E, which offer improved refrigeration capacity, efficiency, and environmental sustainability by achieving low GWP, low toxicity, and low flammability, along with reduced temperature glide, making them suitable for various thermal management applications.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Object-affected harmful factors

If R-134a is used for air conditioning, then cooling performance is achieved, but global warming potential is high

Engineering Contradiction:
Improveglobal warming potentialVSAvoidcooling performance
Core Design Contradiction:
Object-affected harmful factorsVSReliability

Solution Approach 1:

The patent changes the chemical composition parameters by replacing R-134a with a blend of HFO-1234yf, HFO-1132E, and HFC-152a. This composition change reduces GWP from 143 (R-134a) to below 100 (blend), while maintaining cooling performance through synergistic effects of the blend components.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent uses a composite refrigerant blend combining three different substances (HFO-1234yf, HFO-1132E, and HFC-152a) in specific proportions. This composite approach allows the system to achieve both low GWP and reliable cooling performance that cannot be obtained with single-component refrigerants alone.

Inventive Principle:
Principle #40Composite materials

2Weight of moving object

If ICE size is reduced or eliminated to decrease vehicle weight, then electric drive cycle increases, but heating capability is lost

Engineering Contradiction:
Improvevehicle weightVSAvoidpassenger cabin heating
Core Design Contradiction:
Weight of moving objectVSTemperature

Solution Approach 1:

The patent implements a heat pump system that provides both cooling and heating functions using a single device. The heat pump can operate in reverse cycle mode to provide cabin heating when the ICE is reduced or eliminated, making the thermal management system universal for both cooling and heating needs.

Inventive Principle:
Principle #6Universality (Multi-functionality)

Solution Approach 2:

The patent replaces the mechanical heating system (which relied on ICE waste heat) with an electrical heat pump system. This substitution allows heating to be achieved through electrical power-driven refrigeration cycle reversal, independent of ICE presence.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

3Productivity

If refrigerant blends are used to improve thermal management, then cooling and heating efficiency increases, but temperature glide increases

Engineering Contradiction:
Improvethermal management efficiencyVSAvoidtemperature glide
Core Design Contradiction:
ProductivityVSStability of the object's composition

Solution Approach 1:

The patent optimizes the composition parameters of the refrigerant blend to achieve a balance between thermal efficiency and temperature glide. By adjusting the ratios of HFO-1234yf, HFO-1132E, and HFC-152a, the system achieves improved volumetric capacity and COP while limiting temperature glide to acceptable levels for automotive applications.

Inventive Principle:
Principle #35Parameter changes

Data Source

PatentUS20250145876A1Compositions of HFO-1234yf, HFO-1132e, and HFC-152a and systems for using the compositions
Publication Date: 2025.05.08 CHEMOURS CO FC LLC THE
  • US20250145876A1 patent drawing
  • US20250145876A1 patent drawing
  • US20250145876A1 patent drawing

AI summary

Environmentally friendly refrigerant blends utilizing refrigerants including 2,3,3,3-tetrafluoropropene (HFO-1234yf), E-1,2-difluoroethylene (HFO-1132E), and 1,1-difluoroethane (HFC-152a). The blends have low GWP, low toxicity, and low flammability with low temperature glide for use in a hybrid, mild hybrid, plug-in hybrid, or full electric vehicles for thermal management (transferring heat from one part of the vehicle to the other) of the passenger compartment providing air conditioning (A/C) or heating to the passenger cabin.