HFO-1234yf Refrigerant Composition With Controlled Impurity Ranges
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Solution Overview
Problem
New environmental regulations necessitate the development of low global warming potential compounds for refrigeration, air-conditioning, and heat pump applications, where existing compounds have limitations in terms of purity and efficiency.
Innovation Solution
A composition comprising HFO-1234yf with additional compounds such as HFO-1234ze, HCFC-243db, HCFO-1233xf, and HCFC-244bb, where these additional compounds are present in small amounts to enhance the performance and purity of HFO-1234yf as a refrigerant, aerosol propellant, and heat transfer fluid.
Engineering Contradictions & Design Principles
Engineering Contradiction Analysis
1Object-affected harmful factors
If existing refrigerant compounds are used, then refrigeration and air-conditioning functions are provided, but they have high global warming potential and fail to meet new environmental regulations
Solution Approach 1:
The patent changes the chemical composition parameters by using HFO-1234yf as the primary refrigerant compound and controlling the presence of specific additional compounds within defined concentration ranges. This parameter change achieves low global warming potential while meeting environmental regulation requirements, resolving the contradiction between harmful environmental factors and regulatory compliance.
2Manufacturing precision
If high purity HFO-1234yf is produced through extensive purification, then purity is improved, but manufacturing complexity and cost increase
Solution Approach 1:
Instead of extensive purification to remove all impurities, the patent takes out only the specific additional compounds that are present in small amounts (less than 1 weight percent) and are identified as acceptable. This selective extraction approach maintains sufficient purity for refrigeration applications while avoiding the complexity and cost of complete purification processes.
3Object-affected harmful factors
If HFO-1234yf is used as a refrigerant, then low global warming potential is achieved, but the presence of additional compounds from production processes reduces composition purity
Solution Approach 1:
The patent converts the harmful presence of additional compounds produced during manufacturing into a beneficial specification by defining acceptable concentration ranges for these compounds. Rather than viewing them as impurities to be completely eliminated, the patent specifies that certain additional compounds at less than 1 weight percent are acceptable, thereby maintaining low global warming potential while acknowledging practical manufacturing limitations.
Data Source
Figure 1

AI summary
Disclosed are compositions comprising HCFC-243db and at least one additional compound selected from the group consisting of ethylene, HFC-23, CFC-13, HFC-143a, HFC-152a, HFO-1234yf, HFO-1243zf, HFC-236fa, HCO-1130, HCO-1130a, HFO-1234ze, HFO-1336, HCFC-244bb, HCFC-244db, HFC-245fa, HFC-245cb, HCFC-133a, HCFC-254fb, HCFC-1131, HCFO-1233xf, HCFO-1233zd, HCFO-1242zf, HCFC-253fb, HCFO-1223xd, HCFC-233ab, HCFC-226ba, and HFC-227ca.