HFO-1234yf Refrigerant Composition With Controlled Impurity Ranges

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Solution Overview

Problem

New environmental regulations necessitate the development of low global warming potential compounds for refrigeration, air-conditioning, and heat pump applications, where existing compounds have limitations in terms of purity and efficiency.

Innovation Solution

A composition comprising HFO-1234yf with additional compounds such as HFO-1234ze, HCFC-243db, HCFO-1233xf, and HCFC-244bb, where these additional compounds are present in small amounts to enhance the performance and purity of HFO-1234yf as a refrigerant, aerosol propellant, and heat transfer fluid.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Object-affected harmful factors

If existing refrigerant compounds are used, then refrigeration and air-conditioning functions are provided, but they have high global warming potential and fail to meet new environmental regulations

Engineering Contradiction:
Improveglobal warming potentialVSAvoidcompliance with environmental regulations
Core Design Contradiction:
Object-affected harmful factorsVSReliability

Solution Approach 1:

The patent changes the chemical composition parameters by using HFO-1234yf as the primary refrigerant compound and controlling the presence of specific additional compounds within defined concentration ranges. This parameter change achieves low global warming potential while meeting environmental regulation requirements, resolving the contradiction between harmful environmental factors and regulatory compliance.

Inventive Principle:
Principle #35Parameter changes

2Manufacturing precision

If high purity HFO-1234yf is produced through extensive purification, then purity is improved, but manufacturing complexity and cost increase

Engineering Contradiction:
Improvepurity of HFO-1234yfVSAvoidpurification process complexity
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

Instead of extensive purification to remove all impurities, the patent takes out only the specific additional compounds that are present in small amounts (less than 1 weight percent) and are identified as acceptable. This selective extraction approach maintains sufficient purity for refrigeration applications while avoiding the complexity and cost of complete purification processes.

Inventive Principle:
Principle #2Taking out (Extraction)

3Object-affected harmful factors

If HFO-1234yf is used as a refrigerant, then low global warming potential is achieved, but the presence of additional compounds from production processes reduces composition purity

Engineering Contradiction:
Improveglobal warming potentialVSAvoidcomposition purity
Core Design Contradiction:
Object-affected harmful factorsVSManufacturing precision

Solution Approach 1:

The patent converts the harmful presence of additional compounds produced during manufacturing into a beneficial specification by defining acceptable concentration ranges for these compounds. Rather than viewing them as impurities to be completely eliminated, the patent specifies that certain additional compounds at less than 1 weight percent are acceptable, thereby maintaining low global warming potential while acknowledging practical manufacturing limitations.

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

Data Source

PatentEP4446304A1Compositions comprising 2,3,3,3-tetrafluoropropene
Publication Date: 2024.10.16 THE CHEMOURS CO FC LLC
  • EP4446304A1 patent drawingFigure 1
  • EP4446304A1 patent drawing
  • EP4446304A1 patent drawing

AI summary

Disclosed are compositions comprising HCFC-243db and at least one additional compound selected from the group consisting of ethylene, HFC-23, CFC-13, HFC-143a, HFC-152a, HFO-1234yf, HFO-1243zf, HFC-236fa, HCO-1130, HCO-1130a, HFO-1234ze, HFO-1336, HCFC-244bb, HCFC-244db, HFC-245fa, HFC-245cb, HCFC-133a, HCFC-254fb, HCFC-1131, HCFO-1233xf, HCFO-1233zd, HCFO-1242zf, HCFC-253fb, HCFO-1223xd, HCFC-233ab, HCFC-226ba, and HFC-227ca.