HgZnTe-on-Silicon Detector Assembly for Lower Dislocation Density

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Solution Overview

Problem

Conventional HgCdTe detectors on silicon substrates suffer from reduced performance due to dislocation density and lattice mismatch, leading to mechanical deformation and thermal instability.

Innovation Solution

A HgZnTe detector assembly is proposed, featuring a HgZnTe detector grown on a silicon substrate with a HgZnTe-based buffer layer and optionally a ZnTe passivation layer, utilizing molecular-beam epitaxy, which offers improved mechanical strength, reduced lattice mismatch, and higher dislocation energy compared to HgCdTe detectors.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Area of stationary object

If HgCdTe detectors are used on silicon substrates, then large area focal plane arrays can be manufactured, but dislocation density increases due to lattice mismatch

Engineering Contradiction:
Improvedetector areaVSAvoiddetector performance
Core Design Contradiction:
Area of stationary objectVSReliability

Solution Approach 1:

The patent changes the material composition parameter from HgCdTe to HgZnTe, which has a lattice constant closer to silicon. This parameter change reduces the lattice mismatch and resulting dislocation density while maintaining the ability to manufacture large area detectors on silicon substrates.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent uses a composite buffer layer structure consisting of multiple layers including HgZnTe, ZnTe, and CdTe layers. This composite structure is designed to gradually transition from silicon to the final HgZnTe detector material, reducing thermal stress and dislocation density while enabling large area fabrication.

Inventive Principle:
Principle #40Composite materials

2Area of stationary object

If HgCdTe detectors are used on silicon substrates, then large area focal plane arrays can be manufactured, but mechanical deformation increases due to softer material properties

Engineering Contradiction:
Improvedetector areaVSAvoidmechanical resistance
Core Design Contradiction:
Area of stationary objectVSStrength

Solution Approach 1:

The patent changes the material from HgCdTe to HgZnTe, which has superior mechanical properties including higher hardness and greater resistance to plastic deformation. This parameter change maintains large area detector capability while improving mechanical strength and reducing deformation during fabrication and operation.

Inventive Principle:
Principle #35Parameter changes

3Area of stationary object

If HgCdTe detectors are used on silicon substrates, then large area focal plane arrays can be manufactured, but thermal stability decreases

Engineering Contradiction:
Improvedetector areaVSAvoidthermal stability
Core Design Contradiction:
Area of stationary objectVSStability of the object's composition

Solution Approach 1:

The patent changes the material composition from HgCdTe to HgZnTe, which has higher thermal stability and resistance to thermally-induced dislocations. This parameter change enables large area detectors to maintain compositional stability under thermal stress during fabrication and operation.

Inventive Principle:
Principle #35Parameter changes

4Adaptability or versatility

If HgZnTe detectors are used with direct bond interconnect, then compatibility with ROIC wafers improves, but manufacturing complexity increases

Engineering Contradiction:
Improveinterconnect compatibilityVSAvoidbuffer layer structure
Core Design Contradiction:
Adaptability or versatilityVSDevice complexity

Solution Approach 1:

The patent changes the material from HgCdTe to HgZnTe, which has lattice and thermal properties more compatible with silicon and standard ROIC fabrication processes. This enables direct bond interconnect technology to be applied, improving adaptability despite the complexity of the buffer layer structure.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The HgZnTe detector assembly exhibits enhanced mechanical resistance, thermal stability, and compatibility for direct bond interconnects, resulting in improved performance and reduced dislocation density, enabling effective integration with read-out integrated circuit wafers.

Implementation Method 1

any one of the HgZnTe-based buffer layer, the HgZnTe detector and the passivation layer are grown using molecular-beam epitaxy

Methodology Applied
Scientific EffectMolecular-beam epitaxy: Epitaxy

Data Source

PatentUS20240170600A1HgZnTe DETECTOR ON SILICON SUBSTRATE
Publication Date: 2024.05.23 RAYTHEON CO
  • US20240170600A1 patent drawing
  • US20240170600A1 patent drawing
  • US20240170600A1 patent drawing

AI summary

A HgZnTe detector on a silicon substrate provides significant advantages over conventionally used HgCdTe detectors on silicon substrates, as HgZnTe is a harder material than HgCdTe, and has less lattice mismatch with silicon than HgCdTe. HgZnTe also has a higher dislocation energy than HgCdTe, as well as a higher thermal stability than HgCdTe, making it more resistant to dislocation.