High-k Dielectric Etch Stop Liners for Transistor Spacers

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Solution Overview

Problem

The scaling of transistor elements in integrated circuits leads to challenges such as short channel effects, increased leakage currents, and dopant diffusion issues due to the limitations of conventional etch stop materials like silicon dioxide, resulting in degraded transistor performance and material loss during processing.

Innovation Solution

The use of high-k dielectric materials as etch stop liners in semiconductor devices allows for reduced thickness without significant material loss, providing superior etch resistivity and diffusion blocking capabilities, thereby enhancing transistor performance and reducing surface topography.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Loss of substance

If conventional etch stop materials like silicon dioxide are used, then etch stop capability is provided, but material loss and dopant out-diffusion occur during processing

Engineering Contradiction:
Improvematerial lossVSAvoidetch stop capability
Core Design Contradiction:
Loss of substanceVSReliability

Solution Approach 1:

The patent changes the material parameter from conventional silicon dioxide to high-k dielectric materials (such as hafnium oxide, tantalum oxide, or zirconium oxide) which have significantly different etch resistance properties. These high-k materials provide superior etch stop capability while reducing material loss during plasma etching processes, directly resolving the contradiction between etch stop reliability and material loss.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs composite structures where high-k dielectric materials are integrated with existing spacer and etch stop layers. This composite approach combines the diffusion blocking properties of high-k materials with the structural functions of conventional spacer materials, achieving both reliable etch stop capability and reduced dopant out-diffusion without completely replacing the existing material system.

Inventive Principle:
Principle #40Composite materials

2Length of stationary object

If etch stop liner thickness is reduced to minimize material loss, then surface topography is improved, but etch stop capability may be compromised

Engineering Contradiction:
Improveetch stop liner thicknessVSAvoidetch stop capability
Core Design Contradiction:
Length of stationary objectVSReliability

Solution Approach 1:

The patent changes the material composition parameter of the etch stop liner from silicon dioxide to high-k dielectric materials. This parameter change enables the liner to maintain superior etch stop capability at reduced thicknesses, because high-k materials exhibit different etch kinetics and provide better etch front stopping ability. Thus, both reduced thickness and maintained etch stop capability are achieved simultaneously.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent uses thin films of high-k dielectric materials that can be deposited in controlled thicknesses. These thin etch stop liners serve their purpose effectively during the etch process and can be selectively removed or integrated into subsequent processing steps, providing a disposable yet highly effective etch stop solution that minimizes material loss and surface topography issues.

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

3Reliability

If high dose dopants are introduced into crystalline substrate area, then conductivity is improved, but crystal structure damage is generated

Engineering Contradiction:
ImproveconductivityVSAvoidcrystal structure
Core Design Contradiction:
ReliabilityVSStability of the object's composition

Solution Approach 1:

The patent introduces dopants into the crystalline substrate area during ion implantation before the high-k dielectric etch stop liner is fully processed. The high-k material then serves as a diffusion barrier that prevents further dopant migration during subsequent high-temperature processing steps. This preliminary doping action achieves the desired conductivity while the high-k liner protects the crystal structure from further damage during later annealing processes.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The high-k dielectric etch stop liner acts as an intermediary diffusion barrier between the doped crystalline region and the overlying spacer structures. This intermediary layer prevents dopant out-diffusion during subsequent processing, thereby maintaining the conductivity improvements achieved through high-dose implantation while protecting the crystal structure from further degradation.

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach enables superior etch stop capabilities, reducing dopant out-diffusion and material loss, and improving the integrity of transistor structures, leading to enhanced performance and reduced variability in semiconductor devices.

Implementation Method 1

high-k dielectric materials may be used as an efficient etch stop liner during the spacer patterning, since these materials have significantly different etch characteristics in view of a plurality of well-established plasma assisted etch recipes

Methodology Applied
Scientific EffectEtch selectivity:

Implementation Method 2

providing superior etch resistivity and diffusion blocking capabilities

Methodology Applied
Scientific EffectDiffusion blocking: Diffusion Barrier

Implementation Method 3

patterning a spacer element, the previously obtained device topography may be advantageously used in order to form the spacer elements in a self-aligned manner on the basis of plasma assisted dry etch techniques

Methodology Applied
Scientific EffectPlasma etching: Plasma

Data Source

PatentUS8198166B2Using high-k dielectrics as highly selective etch stop materials in semiconductor devices
Publication Date: 2012.06.12 GLOBALFOUNDRIES US INC
  • US8198166B2 patent drawing
  • US8198166B2 patent drawing
  • US8198166B2 patent drawing

AI summary

A spacer structure in sophisticated semiconductor devices is formed on the basis of a high-k dielectric material, which provides superior etch resistivity compared to conventionally used silicon dioxide liners. Consequently, a reduced thickness of the etch stop material may nevertheless provide superior etch resistivity, thereby reducing negative effects, such as dopant loss in the drain and source extension regions, creating a pronounced surface topography and the like, as are typically associated with conventional spacer material systems.