High-K Gate Dielectric Annealing for Low Diffusion FinFET Gates

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Solution Overview

Problem

Current semiconductor manufacturing processes face challenges in minimizing gate dielectric loss and dopant diffusion during metal gate patterning, particularly due to the limitations in crystallization and annealing temperatures, which affect the integration density and performance of FinFETs.

Innovation Solution

The method involves depositing a gate dielectric layer along the sidewalls and top surface of a fin, followed by microsecond annealing at temperatures between 1000° C to 1150° C to enhance crystallization and reduce dopant diffusion, allowing for higher annealing peak temperatures while minimizing drain-induced barrier lowering effects.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Loss of energy

If conventional annealing processes are used during metal gate patterning, then gate dielectric loss is reduced, but dopant diffusion increases and crystallization is insufficient

Engineering Contradiction:
Improvegate dielectric lossVSAvoiddopant diffusion control
Core Design Contradiction:
Loss of energyVSManufacturing precision

Solution Approach 1:

The patent applies rapid thermal annealing (RTA) with a temperature ramp rate of at least 100°C per second, heating to a peak temperature between 700°C and 1100°C and maintaining it for 1 second to 10 minutes. This parameter change enables sufficient crystallization of the gate dielectric layer while minimizing dopant diffusion, resolving the contradiction between reducing gate dielectric loss and controlling dopant diffusion.

Inventive Principle:
Principle #35Parameter changes

2Strength

If higher annealing peak temperatures are used to improve crystallization, then gate dielectric strength increases, but dopant diffusion and drain-induced barrier lowering effects worsen

Engineering Contradiction:
Improvegate dielectric strengthVSAvoiddopant diffusion and drain-induced barrier lowering
Core Design Contradiction:
StrengthVSObject-generated harmful factors

Solution Approach 1:

The patent employs periodic rapid thermal annealing cycles with controlled peak temperatures between 700°C and 1100°C maintained for 1 second to 10 minutes, followed by rapid cooling. This periodic action allows the gate dielectric to achieve sufficient crystallization and strength while the brief exposure time at high temperature minimizes dopant diffusion and drain-induced barrier lowering effects.

Inventive Principle:
Principle #19Periodic action

3Manufacturing precision

If conventional annealing temperatures are used, then dopant diffusion is minimized, but gate dielectric crystallization and strength are insufficient

Engineering Contradiction:
Improvedopant diffusion controlVSAvoidgate dielectric strength
Core Design Contradiction:
Manufacturing precisionVSStrength

Solution Approach 1:

The patent implements rapid thermal annealing with a minimum temperature ramp rate of 100°C per second, achieving peak temperatures between 700°C and 1100°C and maintaining them for 1 second to 10 minutes. This parameter change enables the gate dielectric to achieve sufficient crystallization and strength while the rapid heating and cooling minimize dopant diffusion.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach results in a stronger gate dielectric layer with reduced loss during metal gate patterning, improved crystallinity, and lower risk of performance degradation, enabling higher integration density and better device performance.

Implementation Method 1

performing a first annealing process on the first high-k dielectric layer; performing a second annealing process on the first high-k dielectric layer and the second high-k dielectric layer

Methodology Applied
Scientific EffectAnnealing: Annealing

Implementation Method 2

after the second annealing process the first high-k dielectric layer and the second high-k dielectric layer have a combined crystallinity that is higher than 70 percent

Methodology Applied
Scientific EffectCrystallization: Crystallisation

Data Source

PatentUS20240297084A1High-K Gate Dielectric and Method Forming Same
Publication Date: 2024.09.05 TAIWAN SEMICONDUCTOR MANUFACTURING CO LTD
  • US20240297084A1 patent drawing
  • US20240297084A1 patent drawing
  • US20240297084A1 patent drawing

AI summary

A method includes depositing a first high-k dielectric layer over a first semiconductor region, performing a first annealing process on the first high-k dielectric layer, depositing a second high-k dielectric layer over the first high-k dielectric layer; and performing a second annealing process on the first high-k dielectric layer and the second high-k dielectric layer.