High-K Gate Stack Dipole Induction Layer for Threshold Voltage Control

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

High-K gate stacks in MOSFET devices face challenges in controlling threshold voltage and channel carrier mobility due to mobility degradation caused by remote phonon scattering and charge trapping, with existing solutions either affecting both nFET and pFET devices or limiting device scalability.

Innovation Solution

A method involving the formation of a high-K gate stack with a dipole induction layer, comprising a high-K metallic oxide with higher oxygen vacancy affinity and lower diffusivity, positioned between the gate electrode and substrate to control threshold voltage and improve mobility by accumulating oxygen vacancies and creating a dipole field, applicable to both n-type and p-type devices.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If high-K metallic oxide layers are formed on silicon substrate to increase dielectric constant, then gate leakage is reduced, but channel carrier mobility is severely degraded due to remote phonon scattering

Engineering Contradiction:
Improvegate leakageVSAvoidremote phonon scattering
Core Design Contradiction:
ReliabilityVSObject-generated harmful factors

Solution Approach 1:

A dipole induction layer is introduced as an intermediary between the high-K metallic oxide gate dielectric and the silicon channel. This layer creates a dipole field that repels oxygen vacancies and phonons away from the channel interface, thereby reducing remote phonon scattering and improving carrier mobility while maintaining the high dielectric constant benefit of the gate stack

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The dipole induction layer is positioned specifically at the critical interface region between the gate dielectric and silicon channel, where it locally modifies the electric field distribution and phonon scattering characteristics without affecting the bulk properties of the high-K dielectric material

Inventive Principle:
Principle #3Local quality

2Adaptability or versatility

If HfO2 gate dielectric is used to achieve high dielectric constant, then device scalability is improved, but threshold voltage control becomes difficult due to charge trapping

Engineering Contradiction:
Improvedevice scalabilityVSAvoidthreshold voltage control
Core Design Contradiction:
Adaptability or versatilityVSManufacturing precision

Solution Approach 1:

The dipole induction layer acts as a mediator that prevents charge trapping at the high-K dielectric/silicon interface by creating a dipole field that repels oxygen vacancies and trapped charges, thereby enabling precise threshold voltage control while maintaining the scalability benefits of HfO2 gate dielectric

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The dipole induction layer converts the potentially harmful effect of oxygen vacancies and charge trapping into a beneficial dipole field that improves threshold voltage control by repelling charges away from the channel interface

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach effectively shifts the threshold voltage to a desired level and enhances channel mobility by confining oxygen vacancies, providing a flexible and efficient mechanism for both nFET and pFET devices, while maintaining device scalability.

Implementation Method 1

forming a composite layer directly on the first layer, the composite layer including a second high-K metallic oxide layer formed directly on a dipole induction layer, the dipole induction layer including a high-K metallic oxide having higher oxygen vacancy affinity and lower oxygen vacancy diffusivity than the first and second layers

Methodology Applied
Scientific EffectDipole induction: Electrostatic Induction

Implementation Method 2

the dipole induction layer including a high-K metallic oxide having higher oxygen vacancy affinity and lower oxygen vacancy diffusivity than the first and second layers

Methodology Applied
Scientific EffectOxygen vacancy affinity: Adsorption

Data Source

PatentUS8273618B2Formation of high-K gate stacks in semiconductor devices
Publication Date: 2012.09.25 INTERNATIONAL BUSINESS MACHINE CORPORATION
  • US8273618B2 patent drawing
  • US8273618B2 patent drawing
  • US8273618B2 patent drawing

AI summary

A method of forming a high-K gate stack for a MOSFET device to control the threshold voltage for the MOSFET device. A first high-K metallic oxide layer is formed on a semiconductor substrate. At least one composite layer is then formed directly on the first layer. The composite layer is composed of a second high-K metallic oxide layer formed directly on a dipole induction layer. The dipole induction layer includes a high-K metallic oxide having higher oxygen vacancy affinity and lower oxygen vacancy diffusivity than the first and second layers. A metallic gate electrode is then formed on the composite layer. Formation of the various layers is such as to position the dipole induction layer of the composite layer between the gate electrode and substrate so as to shift the threshold voltage to a desired level. A high-K gate stack in a MOSFET device formed by the above method is also provided.