High-Pressure Nitrogen Distillation Without a Product Compressor

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Solution Overview

Problem

Existing nitrogen production under high pressure often requires additional energy loss and the use of a nitrogen compressor, which reduces the recovery ratio and increases manufacturing costs.

Innovation Solution

A process involving a high pressure distillation column and a medium pressure column, where oxygen-enriched liquid is reduced in pressure, expanded to produce power, and recycled to improve nitrogen recovery, eliminating the need for a nitrogen compressor by optimizing the system's thermal equilibrium and refrigeration balance.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If a nitrogen compressor is added to meet customer demand for high-pressure nitrogen, then the nitrogen production capacity is improved, but the manufacturing cost and device complexity increase

Engineering Contradiction:
Improvenitrogen production capacityVSAvoiddevice complexity
Core Design Contradiction:
ProductivityVSDevice complexity

Solution Approach 1:

The patent divides the distillation system into two separate columns: a first distillation column operating at high pressure and a second distillation column operating at medium pressure. This segmentation allows each column to be optimized for its specific pressure range, with the high-pressure column producing high-pressure nitrogen directly without requiring an additional compressor, thereby maintaining productivity while reducing device complexity

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The patent introduces a pressure dimension differentiation by operating the two distillation columns at different pressure levels (high pressure vs. medium pressure). This dimensional change enables the system to produce high-pressure nitrogen directly from the high-pressure column, eliminating the need for post-compression and reducing overall device complexity

Inventive Principle:
Principle #17Another dimension (Dimensionality change)

2Stress or pressure

If the top condenser pressure is increased to supply high pressure nitrogen, then the nitrogen production pressure is improved, but the recovery ratio and specific power deteriorate

Engineering Contradiction:
Improvenitrogen production pressureVSAvoidspecific power
Core Design Contradiction:
Stress or pressureVSLoss of energy

Solution Approach 1:

By segmenting the distillation system into high-pressure and medium-pressure columns, the patent allows the high-pressure column to operate at the required nitrogen production pressure (5-10 bars or higher) while the medium-pressure column handles the oxygen-enriched liquid at lower pressure. This segmentation maintains energy efficiency by avoiding excessive condenser pressure increases that would worsen specific power consumption

Inventive Principle:
Principle #1Segmentation

3Device complexity

If the vaporized oxygen enriched liquid is expanded in a valve instead of an expander, then the device complexity is reduced, but energy is lost

Engineering Contradiction:
Improvedevice complexityVSAvoidenergy loss
Core Design Contradiction:
Device complexityVSLoss of energy

Solution Approach 1:

The patent implements a self-service energy recovery system where the vaporized oxygen-enriched liquid from the high-pressure column is expanded through an expander that generates power. This generated power is then used to drive the cold compressor that compresses the waste vapor stream, creating a self-sufficient energy loop that reduces external power requirements and eliminates energy loss

Inventive Principle:
Principle #25Self-service

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This process enhances nitrogen recovery ratio at higher pressures, reducing energy loss and manufacturing costs, allowing for efficient production of high-pressure nitrogen without additional compressors.

Implementation Method 1

cooling feed air to substantially the dew-point thereof

Methodology Applied
Scientific EffectHeat transfer: Heat Exchanger

Implementation Method 2

cooling feed air to substantially the dew-point thereof

Methodology Applied
Scientific EffectCondensation: Condensation

Implementation Method 3

reducing the pressure of said oxygen enriched liquid to a medium pressure

Methodology Applied
Scientific EffectPressure reduction: Depressurisation

Implementation Method 4

reducing the pressure of said oxygen enriched liquid to a medium pressure

Methodology Applied
Scientific EffectJoule-Thomson effect: Joule-Thomson Effect

Implementation Method 5

heating said waste vapor stream

Methodology Applied
Scientific EffectHeat transfer: Heat Exchanger

Implementation Method 6

expanding at least part of the heated waste vapor stream to produce power

Methodology Applied
Scientific EffectWork extraction: Turbine

Implementation Method 7

compressing a vapor stream removed from the medium pressure column in a cold compressor

Methodology Applied
Scientific EffectCompression: Compression

Implementation Method 8

pumping said withdrawn liquid to said high pressure and injecting it at the top of the high pressure column

Methodology Applied
Scientific EffectPressure increase: Pump

Data Source

PatentEP2463232B1Process and installation for producing high-pressure gaseous nitrogen
Publication Date: 2014.02.12 LAIR LIQUIDE SA POUR LETUDE & LEXPLOITATION DES PROCEDES GEORGES CLAUDE
  • EP2463232B1 patent drawingFigure 1
  • EP2463232B1 patent drawingFigure 2

AI summary

A process for producing high pressure gaseous nitrogen, comprising : cooling feed air to substantially the dew-point thereof, introducing at least a portion of said air at a base of a high pressure column (107, 207); removing a oxygen enriched liquid from the base of said high pressure column; reducing the pressure of said oxygen enriched liquid to a medium pressure, wherein said medium pressure is between said high pressure and atmospheric pressure, introducing said oxygen enriched liquid at an intermediate place of a medium pressure column (106, 206); reducing the pressure of at least a part of a liquid removed from the base of said medium pressure column to a low pressure to cool a top condenser of said medium pressure column and to form a waste vapor stream; compressing a vapor stream removed from the medium pressure column in a cold compressor (105, 205), cooling said compressed vapor stream, and introducing it into the base of the high pressure column; heating said waste vapor stream, and expanding at least part of the heated waste vapor stream to produce power; withdrawing liquid from the top of said medium pressure column, pumping said withdrawn liquid to said high pressure and injecting it at the top of the high pressure column; and withdrawing product gaseous nitrogen from the top of the high pressure column.