Batchwise High-Shear Mixer for Silicone Composition

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Solution Overview

Problem

Current methods for producing silicone compositions face challenges in achieving high productivity while maintaining quality consistency, particularly with high bulk density fillers, leading to prolonged processing times and increased energy consumption.

Innovation Solution

A method involving a batchwise high-shear mixer with a rotatable mixing pan, eccentric high-speed agitator, and stationary scraper for kneading organopolysiloxane and fillers with a BET surface area of at least 10 m²/g, allowing for efficient mixing and heat treatment under controlled conditions to produce a silicone composition of consistent quality.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If batchwise large-size mixers are used to produce compounds of consistent quality, then manufacturing precision is improved, but productivity deteriorates due to very long powder mixing times

Engineering Contradiction:
Improvequality consistencyVSAvoidproductivity
Core Design Contradiction:
Manufacturing precisionVSProductivity

Solution Approach 1:

The patent changes the mixing parameters by using high shear stress (intense mechanical action) combined with high temperature (100-200°C) and reduced pressure conditions. This parameter transformation allows rapid mixing of fillers with high bulk density while maintaining compound quality consistency, resolving the contradiction between manufacturing precision and productivity

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs periodic heating and heat treatment cycles during the mixing process. The intermittent application of thermal energy accelerates the mixing kinetics and promotes uniform filler distribution, enabling both high productivity and consistent quality output

Inventive Principle:
Principle #19Periodic action

2Productivity

If mixing vessel volume is increased to increase productivity, then productivity is improved, but use of energy deteriorates due to accordingly higher power requirements

Engineering Contradiction:
ImproveproductivityVSAvoidenergy consumption
Core Design Contradiction:
ProductivityVSUse of energy by moving object

Solution Approach 1:

The patent transforms the mixing approach by applying high temperature and reduced pressure parameters, which dramatically accelerates the mixing process. This allows achieving high productivity in a compact mixer volume, thereby avoiding the energy penalty associated with large-scale mixers while maintaining high output rates

Inventive Principle:
Principle #35Parameter changes

3Productivity

If twin-screw continuous kneader/extruder units are used to achieve high productivity, then productivity is improved, but manufacturing precision deteriorates due to problems in metering, feeding, and pumping of filler

Engineering Contradiction:
ImproveproductivityVSAvoidquality consistency
Core Design Contradiction:
ProductivityVSManufacturing precision

Solution Approach 1:

The patent extracts the filler addition step from the continuous processing line and performs it separately in the batchwise mixer before combining with the organopolysiloxane. This separation eliminates the metering and feeding problems inherent in continuous systems, ensuring both high productivity and consistent quality

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The patent performs preliminary mixing of the filler with a portion of the organopolysiloxane to form a pre-mixed composition, which is then combined with the remaining organopolysiloxane. This preliminary action ensures uniform filler distribution and eliminates quality consistency issues while maintaining high productivity

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This method enables the preparation of silicone compositions with improved fluidity and physical properties within a short time, reducing energy consumption and accommodating various types of compositions, thus enhancing productivity and energy efficiency.

Implementation Method 1

batchwise high-shear mixer with a rotatable mixing pan, eccentric high-speed agitator

Methodology Applied
Scientific EffectHigh-shear mixing: Shear Stress

Implementation Method 2

kneading organopolysiloxane and fillers with a BET surface area of at least 10 m²/g, allowing for efficient mixing and heat treatment

Methodology Applied
Scientific EffectViscous heating: Viscous Heating

Data Source

PatentEP2290006B1Method for preparing silicone composition
Publication Date: 2015.03.04 SHIN ETSU CHEMICAL CO LTD
  • EP2290006B1 patent drawingFigure 1

AI summary

A silicone composition comprising an organopolysiloxane containing at least two silicon-bonded alkenyl and/or hydroxyl groups in the molecule and a filler having a BET surface area of at least 10 m2/g is prepared by kneading the components in a batchwise high-shear mixer. The mixer includes a rotatable mixing pan (1), a high-speed rotation agitator (3) disposed eccentrically in the pan, and a stationary scraper (4) disposed in the pan for creating a vertical counterflow.