High Solids PAE Resin Adhesive for Wood Composites

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Solution Overview

Problem

Current adhesives based on polyamidoamine-epihalohydrin (PAE) resins face limitations in achieving high solids content while maintaining stability and low viscosity, which is essential for effective bonding in composite materials, particularly in wood-based products, as they often suffer from high viscosity and poor aging stability at elevated temperatures.

Innovation Solution

Development of high solids PAE resins with a solids content of greater than 40% and a combination of PAE and protein sources, such as soy protein, that exhibit improved aging stability and low viscosity, enabling the creation of adhesives with at least 45% solids content, suitable for use in wood-containing composite materials.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If PAE resins with high solids content are used, then adhesive strength and productivity are improved, but viscosity increases and aging stability deteriorates

Engineering Contradiction:
Improveadhesive solids contentVSAvoidaging stability
Core Design Contradiction:
ProductivityVSStability of the object's composition

Solution Approach 1:

The patent changes the molecular weight parameter of the PAE resin to achieve the desired balance. Specifically, it uses PAE resins with molecular weights between 500-5000 g/mol, which is lower than conventional resins. This parameter change allows the resin to maintain low viscosity and good aging stability even at high solids content (40-70%), thereby resolving the contradiction between productivity and stability.

Inventive Principle:
Principle #35Parameter changes

2Productivity

If PAE resins with high solids content are used, then adhesive strength is improved, but viscosity increases

Engineering Contradiction:
Improveadhesive solids contentVSAvoidviscosity
Core Design Contradiction:
ProductivityVSEase of operation

Solution Approach 1:

The patent changes the molecular weight parameter of the PAE resin to achieve the desired balance. Specifically, it uses PAE resins with molecular weights between 500-5000 g/mol, which is lower than conventional resins. This parameter change allows the resin to maintain low viscosity and good aging stability even at high solids content (40-70%), thereby resolving the contradiction between productivity and stability.

Inventive Principle:
Principle #35Parameter changes

3Ease of operation

If conventional low molecular weight PAE resins are used, then viscosity is reduced, but aging stability deteriorates

Engineering Contradiction:
ImproveviscosityVSAvoidaging stability
Core Design Contradiction:
Ease of operationVSStability of the object's composition

Solution Approach 1:

The patent optimizes the molecular weight parameter within a specific range (500-5000 g/mol) rather than simply minimizing it. This optimized parameter range achieves the desired balance between viscosity and aging stability, resolving the contradiction between ease of operation and stability.

Inventive Principle:
Principle #35Parameter changes

4Productivity

If high solids adhesive formulations are used, then productivity is improved, but manufacturing precision deteriorates due to poor stability

Engineering Contradiction:
Improvesolids contentVSAvoidadhesive property consistency
Core Design Contradiction:
ProductivityVSManufacturing precision

Solution Approach 1:

The patent changes the molecular weight parameter of the PAE resin to a specific range (500-5000 g/mol) that enables high solids content formulations to maintain good aging stability. This parameter change ensures that adhesive properties remain consistent during storage and application, thereby resolving the contradiction between productivity and manufacturing precision.

Inventive Principle:
Principle #35Parameter changes

Data Source

PatentEP2531546B1Adhesive compositions
Publication Date: 2014.12.03 SOLENIS TECHNOLOGIES CAYMAN LP
  • EP2531546B1 patent drawing
  • EP2531546B1 patent drawing
  • EP2531546B1 patent drawing

AI summary

The invention is directed to composition, preparation and use of composite materials based on an adhesive with so?ds levels above 45% by weight that contain stable pojyamidoamine-epihalohydrin resins (PAE resins) of solids greater than 40% where the relative high solids of the PAE enables the high solids content of the adhesive. Furthermore, at least 45% of the solids portion of the adhesive is made up of a combination of the solids of the PAE resin and the solids of the protein source. The invention is also directed an adhesive comprised of the PAE in combination with a soy protein source. The invention is also directed toward use of the adhesive in composite materials and in particular wood containing composite materials, and more specifically wood fiber or particle based composites.