High-Strength Steel Zinc-Iron Coating via Controlled Pre-Oxidation

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Solution Overview

Problem

Existing methods for applying a zinc-iron-based coating to high-strength steels with high alloying elements like silicon, manganese, and chromium face adhesion issues that compromise the strength and surface properties of the steel.

Innovation Solution

A manufacturing process involving pre-oxidation and controlled atmospheric conditions during heating to form a protective Fe oxide layer, followed by selective removal, ensures good adhesion of the zinc-iron coating without adversely affecting the steel's strength properties.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If high-strength steel with high alloying elements (silicon, manganese, chromium) is hot-dip coated with zinc-iron-based coating, then corrosion protection is improved, but adhesion of the coating deteriorates

Engineering Contradiction:
Improvecorrosion protectionVSAvoidcoating adhesion
Core Design Contradiction:
ReliabilityVSStrength

Solution Approach 1:

The steel surface is pre-oxidized by heating in an oxidizing atmosphere before coating to form a Fe oxide layer. This preliminary oxidation prevents selective oxidation of alloying elements during subsequent coating processes, ensuring good adhesion of the zinc-iron-based coating while maintaining corrosion protection.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The atmosphere composition and temperature are controlled during heating to achieve desired oxidation state. By adjusting the oxidizing atmosphere parameters (oxygen content, temperature, holding time), a controlled Fe oxide layer is formed that improves coating adhesion without compromising the steel's mechanical properties.

Inventive Principle:
Principle #35Parameter changes

2Reliability

If high-strength steel with high alloying elements is hot-dip coated with zinc-iron-based coating, then corrosion protection is improved, but surface quality deteriorates

Engineering Contradiction:
Improvecorrosion protectionVSAvoidsurface quality
Core Design Contradiction:
ReliabilityVSManufacturing precision

Solution Approach 1:

The steel surface is pre-oxidized by heating in an oxidizing atmosphere before coating to form a Fe oxide layer. This preliminary oxidation prevents selective oxidation of alloying elements during subsequent coating processes, ensuring good adhesion of the zinc-iron-based coating while maintaining corrosion protection.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The atmosphere composition and temperature are controlled during heating to achieve desired oxidation state. By adjusting the oxidizing atmosphere parameters (oxygen content, temperature, holding time), a controlled Fe oxide layer is formed that improves coating adhesion without compromising the steel's mechanical properties.

Inventive Principle:
Principle #35Parameter changes

3Strength

If selective oxidation of alloying elements occurs during coating process, then coating adhesion deteriorates, but surface defects increase

Engineering Contradiction:
Improvecoating adhesionVSAvoidsurface defects
Core Design Contradiction:
StrengthVSManufacturing precision

Solution Approach 1:

An oxidizing atmosphere is used during heating to form a protective Fe oxide layer on the steel surface. This controlled oxidizing environment prevents selective oxidation of alloying elements (silicon, manganese, chromium) that would otherwise occur during coating, thereby avoiding surface defects and ensuring uniform coating adhesion.

Inventive Principle:
Principle #39Inert atmosphere (Inert environment)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The process achieves a high-strength steel with good forming properties and improved adhesion of the zinc-iron coating, maintaining mechanical integrity and surface quality.

Implementation Method 1

the flat steel product is deliberately pre-oxidized during heating. This results in a predominantly external Fe oxide layer

Methodology Applied
Scientific EffectOxidation: Oxidation

Implementation Method 2

This oxide layer is then selectively removed in a later step by re-oxidation

Methodology Applied
Scientific EffectReduction: Reduction

Data Source

PatentEP4592409A1Fire-coated high strength steel with good surface and deformation properties with zinc-iron based coating
Publication Date: 2025.07.30 THYSSENKRUPP STEEL EUROPE AG PATENTE PATENT DEPARTMENT
  • EP4592409A1 patent drawing
  • EP4592409A1 patent drawing
  • EP4592409A1 patent drawing

AI summary

The present invention relates to a hot-dip coated, high-strength steel with good forming and surface properties, its manufacturing process, and a component made from the steel. The coated steel exhibits good results in the powdering test.